The invention discloses a method for treating
potassium chloride residues in an organic fluorination reaction. The
potassium chloride residues are soaked with water in a soaking kettle,
potassium chloride,
potassium fluoride and
sulfolane are dissolved in the water,
carbide and water-insoluble organic impurities of
tar are filtered and separated, the impurities are washed in hot water and then sent to a qualified
solid waste treatment plant, and the washing water is used for soaking of the residues; soaking solutions enter an extraction kettle,
sulfolane dissolved in water is extracted with an
organic solvent and stands still for layering, an
oil phase is desolventized, the
organic solvent is recycled and returned for extraction, and the remainder is
sulfolane; a water phase enters a settlement kettle, and precipitants are added into the settlement kettle and stirred until a
precipitation reaction is sufficient; sediments are separated, washed and dried to obtain
calcium fluoride, and the washing water is used for soaking of the residues; separating media enter an
evaporator and are condensed to crystalize and dried centrifugally, and potassium chloride is obtained. According to the method, sulfolane, potassium chloride and
potassium fluoride in the residues are all converted into qualified chemical materials except the organic impurities, so that the risk of environmental
pollution is eliminated and considerable
economic benefits are achieved.