The invention belongs to the field of nuclear data measurement. In order to solve the problem of complicated operation of an existing separation method, the invention provides a group separation method. The group separation method comprises the following steps: 1, preparing a mixed carrier solution; 2, preparing a sample to be separated; 3, filling into an HZ201 anion resin column, and leaching with 7 to 10mol / L hydrochloric acid, so as to obtain an Ag solution; 4, leaching with 1 to 3mol / L hydrochloric acid, so as to obtain a Pu-containing solution; 5, leaching with concentrated hydrochloricacid to obtain a solution containing Pd and Cd; 6, leaching with 1 to 2mol / L hydrochloric acid and then leaching with 8 to 10mol / L nitric acid; desorbing to obtain an Sn-containing solution; 7, leaching with de-ionized water and then leaching with 0.2 to 1mol / L ammonia water; desorbing to obtain an Sb-containing solution. According to the group separation method, group separation of plutonium, palladium, silver, cadmium, tin and antimony is realized by adopting one HZ201 anion resin column; separation operation is simplified, and the separation efficiency and recycling efficiency are remarkably improved.