The invention provides an acid pickling process for tail gas of an H-acid monosodium salt, and particularly relates to the technical field of production of the H-acid monosodium salt. The process comprises the following process steps of: S1, introducing the tail gas obtained after a neutralization reaction of the H-acid monosodium salt is conducted into a first bath tower, and performing water washing; S2, introducing the tail gas discharged from the first bath tower into a second bath tower, and performing water washing; S3, introducing the tail gas discharged from the second bath tower intoan acid pickling tower, and performing acid pickling; and S4, finally performing adsorption on the tail gas discharged from the acid pickling tower by using molecular sieves, and discharging the adsorbed tail gas. The process has the advantages that the cost is saved, the quality of the treated tail gas is improved, and discharging is more environmentally friendly.