PCT No. PCT / JP95 / 02732 Sec. 371 Date Aug. 28, 1996 Sec. 102(e) Date Aug. 28, 1996 PCT Filed Dec. 27, 1995 PCT Pub. No. WO96 / 20147 PCT Pub. Date Jul. 4, 1996A gas generant for an air, which is improved in the defects of gas generants using sodium azide in a practical use and has stable combustion capability. And a molecular compound comprising (a) a gas generant component, (b) an oxidant component and (c) a reaction accelerator component, preferably represented by the composition formula (I).M.mX.nY(I)[wherein, M is Al Mg, Ca, Cr, Cu, Zn, Mn, Fe, Co, Sr, Ni and another metal components; X is a nitrogen-containing compound having 0 or 1 carbon atom; Y is an anion such as NO3 and ClO; m is a number of 1 to 3; and n is a number 2 to 3].