The invention relates to a high- performance natural non- toxic timber adhesive agent and the preparing method. Said adhesive agent takes water as medium and comprises adhesive agent A and adhesive agent B. said agent A comprises corn starch, amylose, mixing liquid of PVA and PA, acetoacetic ester, butyl acrylate, benzene carbonic acid and citrate, and after second- time grafting and ploymerization, acetylization modification and several- hour stirring under a certain temperature, it is can be got; agent B comprises mixing liquid of PVA and PA, lithium metasilicate, VAC, butyl acrylate, A- 171, OP- 10, and butyl benzoate, and after several- hour stirring under a certain temperature, it is can be got; dispensing agent A and agent B properly and the final product can be got. The adhesive agent is characterized by non- toxic, high strenght, water- proof, antifreezing, stable coagulation. The invention is characterized by nolve idea, regular process, easy operation, low cost, no pollution, and suitability for industrial production. The timber adhesive agent is suited to be used for integration sheet material, finger- joint sheet material, normal adhesive pressing, furniture and instrument, and so on.