The invention discloses a liquid crystal compound, a liquid crystal composition containing the liquid crystal compound and a photoelectric element. The liquid crystal compound is prepared from components in percentage by weight: 6% to 21% of first component (liquid crystal compound) and 79% to 94% of second component; the weight percentage sum of all the components is 100%. The liquid crystal compound provided by the invention has good intermiscibility, broadens a temperature region in low-temperature application and reduces the viscosity; the liquid crystal composition containing the liquid crystal compound reduces Tcn, a low-temperature storage temperature and a low-temperature working temperature of the liquid crystal compound, has a lower viscosity, is beneficial for improving a liquidcrystal display effect and shortening response time, is related to proper optical anisotropy, higher dielectric anisotropy, a lower threshold voltage, a higher VHR (Voltage Holding Ratio), excellentreliability and thermal stability, and is applied to positive TN-TFT (Twisted Nematic Thin Film Transistor), IPS (In-Plane Switching), FFS (Fringing Field Switching), PSA (Polymer-Stabilized) mode liquid crystals.