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Penta-substituted tetrahydropyrimidines with aggregation-induced emission characteristics and preparation method and use thereof

InactiveUS20140051855A1Easy to getSimple and convenient stepOrganic chemistryLuminescent compositionsArylOrganic chemistry
The present invention provides a series of penta-substituted tetrahydropyrimidines with aggregation-induced emission (AIE) characteristics and preparation method and use thereof. The AIE penta-substituted tetrahydropyrimidines have structures shown as formula (I). R1 is selected from a group consisting of linear or branched alkyls and substituted alkyls. R2 and R4 is respectively selected from a group consisting of linear or branched alkyls, substituted alkyls, cycloalkyls, substituted cycloalkyls, aryls, substituted aryls, polycyclic aryls, substituted polycyclic aryls, heterocyclyls, substituted heterocyclyls, aromatic heterocyclyls and substituted aromatic heterocyclyls. R3 is selected from a group consisting of aryls, substituted aryls, polycyclic aryls, substituted polycyclic aryls, aromatic heterocyclyls and substituted aromatic heterocyclyls. The penta-substituted tetrahydropyrimidines can be prepared by multi-component reactions (MCR). There are 1˜3 aryls in the structure of the penta-substituted tetrahydropyrimidines. The penta-substituted tetrahydropyrimidines possess strong AIE properties and can be used for preparing organic electro-luminescence or photo-luminescence devices, or chemical and biological fluorescent sensors or probes.
Owner:SOUTHERN MEDICAL UNIVERSITY

Penta-substituted tetrahydropyrimidines with aggregation-induced emission characteristics and preparation method and use thereof

The present invention provides a series of penta-substituted tetrahydropyrimidines with aggregation-induced emission (AIE) characteristics and preparation method and use thereof. The AIE penta-substituted tetrahydropyrimidines have structures shown as formula (I). R1 is selected from a group consisting of linear or branched alkyls and substituted alkyls. R2 and R4 is respectively selected from a group consisting of linear or branched alkyls, substituted alkyls, cycloalkyls, substituted cycloalkyls, aryls, substituted aryls, polycyclic aryls, substituted polycyclic aryls, heterocyclyls, substituted heterocyclyls, aromatic heterocyclyls and substituted aromatic heterocyclyls. R3 is selected from a group consisting of aryls, substituted aryls, polycyclic aryls, substituted polycyclic aryls, aromatic heterocyclyls and substituted aromatic heterocyclyls. The penta-substituted tetrahydropyrimidines can be prepared by multi-component reactions (MCR). There are 1˜3 aryls in the structure of the penta-substituted tetrahydropyrimidines. The penta-substituted tetrahydropyrimidines possess strong AIE properties and can be used for preparing organic electro-luminescence or photo-luminescence devices, or chemical and biological fluorescent sensors or probes.
Owner:SOUTHERN MEDICAL UNIVERSITY

Flexible horseshoes, method for attaching and device for making

A flexible horseshoe which attaches to a horse hoof by threaded attachment screws. The invention also includes the device for cutting the flexible horseshoes, and the method of mounting the flexible horseshoes.
Owner:BALDWIN J GRANT

Carbonizing Apparatus

This invention provides a carbonizing apparatus for easily carbonizing a material to a desired state of carbonization, which apparatus requires a reduced installation space, and lowers concentration of harmful gases contained in an exhaust gas. The interior of a cylindrical furnace body 82 having a vertical axis is divided by a partition wall 83 into an upper furnace body acting as a combustion section 80 and a lower furnace body acting as a carbonization section 6. The partition wall 83 defines a through hole for supplying distillation gas to the combustion section 80. The carbonization section 6 has a vertical structure, with a supply part 33 disposed in an upper portion for supplying a material under treatment 1, and a carbide take-out part 35 and a first blowoff part 36 of spontaneous combustion air disposed in a lower portion, so that the material under treatment 1 is movable by gravity toward the take-out part 35. An agitating device 39 includes agitating members 43 revolvable about a vertical axis. A premix combustion section 81 is provided on the combustion part 80 side of the partition wall 83 for mixing a distillation gas having passed through the through-hole with an exhaust gas discharged from a discharge part 34 and burning the mixture. Gas having passed through the premix combustion section 81 is supplied to the combustion section 80.
Owner:SUNTORY HLDG LTD

Method and apparatus for producing forging by rotary forging

A cycle is repeated a plurality of times, which includes a forging process for placing a material to be forged in a lower die and pressing the material to be forged in this state and then separating an upper die from the material to be forged; an elevation process for lifting the material to be forged by using an elevation device to separate the material to be forged from the lower die; a rotation process for rotating the material to be forged around its center by using a rotation device; and a lowering process for placing the material to be forged rotated by the elevation device in the lower die.
Owner:HITACHI METALS LTD
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