The invention relates to a method for identifying
polyamide 6 or
polyamide 66 in blended textiles. The method comprises the following steps: (1) a
polyamide 6 or polyamide 66 pure product is taken and a
formic acid solution is added for dissolving, filtering is carried out, a solution is taken and placed in a sample cup, or a polyamide 6 or polyamide 66 pure product is directly taken and placed in a sample cup, a
pyrolysis gas chromatography-
mass spectrometry method is used for carrying out analysis, and a program and a
mass spectrogram of a standard sample are obtained; (2) a blended
textile sample to be measured is taken, a
formic acid solution is added for carrying out immersion treatment, a polyamide component in the sample to be measured is dissolved, filtering is carried out, filtrate of the sample to be measured is placed in a sample cup, the
pyrolysis gas chromatography-
mass spectrometry method is used for carrying out analysis, and a program and a mass
spectrogram of the sample to be measured are obtained; (3) compared with the standard sample, and according to characteristic
pyrolysis substances and
retention time of the sample to be measured as well as
peak area and relative content thereof, identification and analysis of components are carried out. The method has the advantages of simple, sensitive and reliable operation, few
reagent and sample amounts, and little influences on body health of test personnel and surrounding environment.