Patents
Literature
Hiro is an intelligent assistant for R&D personnel, combined with Patent DNA, to facilitate innovative research.
Hiro

61 results about "Glycerol dehydration" patented technology

Hierarchical porous ZSM-5 zeolite catalyst for preparing acrolein through glycerin dehydration as well as preparation method and application of hierarchical porous ZSM-5 zeolite catalyst

The invention belongs to the technical field of chemical catalysts, particularly relates to a hierarchical porous ZSM-5 zeolite catalyst for preparing acrolein through glycerin dehydration as well as a preparation method and application of the hierarchical porous ZSM-5 zeolite catalyst and also provides a method for synthesizing hierarchical porous ZSM-5 zeolite with high crystallinity, controllable particle size, controllable Si / Al ratio and controllable appearance at high yield, low time consumption and low (no) template agent dosage, wherein the hierarchical porous ZSM-5 zeolite is synthesized by introducing a small amount of MFI zeolite crystal seeds and parts of inorganic salt additives to a general synthesis system (a silicon source, an aluminum source, an alkaline source and water) and regulating the synthesis ratio and reaction conditions. The prepared catalyst has the characteristics such as controllable quantity of acid sites, large special surface area, short mass transfer path and the like, can be used for the catalytic reaction for preparing acrolein through the glycerin dehydration and has favorable catalytic activity, selectivity and stability.
Owner:FUDAN UNIV

Process for preparing catalyst used in production of unsaturated aldehyde and/or unsaturated carboxylic acid by dehydration reaction of glycerin, and catalyst obtained

A process for preparing a catalyst used in a production of acrolein and acrylic acid by dehydration reaction of glycerin, characterized by the steps of mixing a solution of heteropolyacid or constituents of heteropolyacid, a solution of at least one metal selected from elements belonging to Group 1 to Group 16 of the Periodic Table of Elements or its onium and a carrier to obtain a solid substance, and then of effecting at least one time of calcination before said solid substance is used in the dehydration reaction of glycerin.A catalyst obtained by the process for use in a production of acrolein and acrylic acid by dehydration reaction of glycerin.A process for preparing acrolein by catalytic dehydration of glycerin carried out in the presence of the catalyst and under a pressurized condition.A process for preparing acrylic acid obtained by oxydation of acrolein obtained.A process for preparing acrylonitrile obtained by ammoxidation of acrolein obtained.
Owner:NIPPON KAYAKU CO LTD

Dolomite-molybdenum trioxide composite catalyst for preparing acrolein through glycerol dehydration and preparation method of dolomite-molybdenum trioxide composite catalyst

The invention discloses a dolomite-molybdenum trioxide composite catalyst for preparing acrolein by glycerol dehydration and a preparation method thereof, and the method comprises the following steps: crushing, grinding, washing and drying natural dolomite, putting into a muffle furnace, heating to 500-700 DEG C, and calcining for 4 hours to obtain calcined dolomite; ammonium molybdate tetrahydrate is dissolved in deionized water, and an ammonium molybdate tetrahydrate solution is obtained; adding the calcined dolomite into an ammonium molybdate tetrahydrate solution, stirring for 4-6 hours, dipping for 24-36 hours, drying in a drying oven, heating to 700 DEG C in a muffle furnace, and calcining for 4 hours, so as to obtain the product. The method is simple in operation method, low in price, clean, efficient and environment-friendly, the required process equipment is also very simple, the time cost can be reduced, and the method is very suitable for large-scale production; by adopting the catalyst disclosed by the invention, the selectivity of acrolein can reach more than 50%, and the catalyst has certain carbon deposition resistance, so that a better technical achievement is achieved.
Owner:ZHEJIANG UNIV OF TECH

Catalyst for dehydration of glycerin, preparation method thereof, and production method of acrolein using the catalyst (as amended)

The present disclosure relates to a catalyst for dehydration of glycerin, a preparation method thereof, and a production method of acrolein using the catalyst.Particularly, the catalyst according to an embodiment of the present disclosure is used in a dehydration reaction of glycerin to exhibit high catalytic activity, a high yield, and high selectivity to acrolein and acrylic acid, and has a longer lifetime compared to the conventional catalysts due to a characteristic that coke carbon cannot be easily deposited on the surface of the catalyst.
Owner:LG CHEM LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products