The invention discloses a synthesis method of
captan or folpet, which comprises the following steps: uniformly mixing 1, 2, 3, 6-tetrahydrophthalimide or
phthalimide, perchloromethyl mercaptan, an
organic solvent and a catalyst to obtain a mixture a; or uniformly mixing 1, 2, 3, 6-tetrahydrophthalimide or
phthalimide, an
organic solvent and a catalyst to obtain a mixture b; dropwise adding an inorganic alkali
aqueous solution into the obtained mixture a, and after dropwise adding, carrying out heat preservation for reaction to synthesize
captan or folpet; or respectively dropwise adding perchloromethyl mercaptan and an
aqueous solution of inorganic alkali into the obtained mixture b, and carrying out heat preservation and reaction after dropwise adding is completed, so as to synthesize
captan or folpet. The
organic solvent, the catalyst and the water are introduced at the same time, the
operation mode is optimized, excessive contact of the raw materials, the product and alkali is reduced,
decomposition of the raw materials and the product is reduced, the product yield is increased, the
wastewater amount is greatly reduced, the
environmental protection requirement is greatly reduced, and the environmental friendliness is greatly improved.