The invention relates to a flexible conductive composite fabric, and preparation and application thereof. The flexible conductive composite fabric comprises a conductive
composite film (1), a base fabric (2) and an
adhesive (3), wherein the base fabric (2) is adhered on the upper and lower surfaces of the conductive
composite film through the
adhesive (3); and two ends of the conductive
composite film (1) are respectively adhered with an
electrode. The flexible conductive composite fabric is prepared through the following steps: impregnating a
carbon nanotube thin film in a
graphene suspension, then taking the
carbon nanotube thin
film out of the
graphene suspension, and carrying out
drying in the air so as to obtain a
carbon nanotube /
graphene composite film; allowing a
polyaniline nanowire array to grow in situ on the surface of the carbon
nanotube / graphene composite film so as to obtain a carbon
nanotube / graphene /
polyaniline composite film; and respectively adhering an
electrode at two ends of the composite film,
coating the base fabric on the upper and lower surfaces of the composite film through the
adhesive, and carrying out curing so as to obtain the flexible conductive composite fabric. The prepared conductive fabric provided by the invention has good
conductivity, can reach 103 S / m to 105 S / m, can bear a certain degree of bending and
compressive deformation, and is extensively applied in the fields of intelligent
textile structures and intelligent materials.