The invention discloses a hydrogen leakage intelligent detection system based on a wireless sensing network, which comprises a hydrogen sensitive probe module, a wireless communication network module and a signal analysis processing module. The hydrogen sensitive probe module is connected with the signal analysis processing module through the wireless communication network module, after completing calibration, the hydrogen sensitive probe module makes filtering and modulation to a data signal, the wireless communication network module acquires and converses the analog data signal, makes processing according to the calibration result, makes judgment according to the processing result, transmits the processing result to a concourse center in a wireless way, and then transmits to a information analysis processing module. The hydrogen leakage intelligent detection system based on a wireless sensing network has the advantages of small size, low cost, convenient installation, strong anti-interference capability, quick response speed, and high safety.