The invention belongs to a building enclosure, and particularly relates to an invisible connected composite plate curtain wall. The composite plate can be manufactured into an oversized unit plate with the same size as a building framework structure, mounting holes are uniformly distributed on the periphery of the plate, and a main body structure is also provided with holes matched with the mounting holes; by adopting a specially designed countersunk head expansion bolt group, the installation operations are all finished on the outer side, and invisibility of curtain wall connectors is realized; and an elastic adjusting shim plate (adjusting shim plate) between the composite plate and the main body structure can make certain adjusting compensation for unevenness of the main body structure. Compared with a glass curtain wall, the invisible connected composite plate curtain wall has the predominant advantages of light weight, high strength, impact resistance, large single plate area, connecting assembly invisibility, regular surface, bright color, safety, reliability, long service life, convenience in construction, high cost performance and the like. The curtain wall and the connecting structure thereof can be applied in the fields of landscape structures, curtain walls of framework structural buildings, enclosures and other similar decorations, and have broad application prospect.