30 results about "Activated complex" patented technology

A red phosphor in the form of a Mn-activated complex fluoride having the formula: A2MF6:Mn wherein M is one or more tetravalent elements selected from Si, Ti, Zr, Hf, Ge, and Sn, and A is one or more alkali metals selected from Li, Na, K, Rb, and Cs, and contains at least Na and / or K, is surface treated with a treating solution containing a surface treating agent selected from an organic amine, quaternary ammonium salt, alkyl betaine or fluorochemical surfactant, alkoxysilane, and fluorinated polymer.

Provided is a method for producing a red phosphor which is a Mn-activated complex fluoride represented by formula (1), A2MF6: Mn (1) (M is one type or more of a tetravalent element selected from Si, Ti, Zr, Hf, Ge, and Sn, and A is one type or more of an alkali metal selected from Li, Na, K, Rb, and Cs, and includes at least Na and / or K.), wherein, as a reactive source, a solid of a complex fluoride represented by formula (2), A2MF6 (2) (M and A are as described above) and a solid of a manganese compound represented by formula (3), A2MnF6 (3) (A is as described above) are mixed and heated at a temperature of from 100 DEG C to 500 DEG C. According to the present invention, a Mn-activated complex fluoride phosphor having favorable luminescence properties can be obtained without using hydrofluoric acid in a main step.

This invention is directed to processes for the formation of ruthenium-containing films on surfaces in atomic layer deposition (ALD) processes. The ALD process includes depositing a surface-activating group on the surface; exposing the deposit of the surface-activating complex to a ruthenium precursor to form a deposited ruthenium complex on the surface; and reacting the deposited ruthenium complex with a reducing agent to form a ruthenium-containing film on the surface. This invention is also directed to ruthenium complexes, RuL2L*, that can be used as ruthenium precursors in these processes.

The present invention provides cosmetic formulations for improving the appearance of the skin, including the facial area. The compositions of the invention provide multiple enhanced technologies that work synergistically to enhance hydration and appearance of the skin. Anti-aging peptides and tissue respiratory factor work together in an HA rich environment to enhance collagen and elastin while beneficial antioxidants protect HA in the skin from damaging exposure.

The invention provides a high-performance ceramic filtering core. The filtering core is prepared from the following ingredients in parts by mass: 25-35 parts of alpha-alumina powder, 25-35 parts of 0.7-micron alpha-alumina powder, 15-25 parts of kaolin, 10-25 parts of magnesian clay, 3-7 parts of dolomite dust, 3-7 parts of talcum powder, and 5-15 parts of a rare earth activated complex antimicrobial agent, wherein the 0.7-micron alpha-alumina powder has grain fineness reaching 0.75 micron. The ceramic filtering core has high filtering precision and long-acting bactericidal property without causing secondary pollution.

Provided is a method for producing a red phosphor which is a Mn-activated complex fluoride represented by formula (1), A2MF6:Mn (1) (M is one type or more of a tetravalent element selected from Si, Ti, Zr, Hf, Ge, and Sn, and A is one type or more of an alkali metal selected from Li, Na, K, Rb, and Cs, and includes at least Na and / or K.), wherein, as a reactive source, a solid of a complex fluoride represented by formula (2), A2MF6 (2) (M and A are as described above) and a solid of a manganese compound represented by formula (3), A2MnF6 (3) (A is as described above) are mixed and heated at a temperature of from 100° C. to 500° C. According to the present invention, a Mn-activated complex fluoride phosphor having favorable luminescence properties can be obtained without using hydrofluoric acid in a main step.

In order to provide crystals of a florigen-activating complex obtained by binding a florigen, a 14-3-3 protein and a bZip transcription factor, and to control the flowering of plants by using said crystals to regulate the mechanisms of interaction between these substances, Hd3a is bound to FD1 via GF14c to form a florigen-activating complex, crystals are prepared from the florigen-activating complex, steric structural information is obtained using the crystals of the florigen-activating complex, and the steric structural information is used to control the interaction mechanism of the florigen and the like in order to thereby control the flowering of a plant.

Provided is a method of producing a Mn-activated complex fluoride phosphor, the method including: mixing a red phosphor as a Mn-activated complex fluoride represented by the following formula (1):K2MF6:Mn  (1)wherein M is one or two or more of tetravalent elements selected from the group consisting of Si, Ti, Zr, Hf, Ge and Sn and necessarily includes Si, with K2MnF6 in solid state and optionally with a hydrogenfluoride represented by the following formula (2):AF.nHF  (2)wherein A is one or two or more of alkali metals and / or ammonium selected from the group consisting of Li, Na, K, Rb and NH4 and necessarily includes K, and n is a number of 0.7 to 4, in solid state; and heating the resulting mixture at a temperature of 100 to 500° C.According to the present invention, it is possible to obtain a Mn-activated complex fluoride phosphor which can be used with smaller amount as compared to those according to the related art.

A red fluorescent substance includes an Mn-activated complex fluoride represented by the formula (1) below: A<1>2MF6:Mn (1) (wherein, letter M is one or two or more of tetravalent elements selected from Si, Ti, Zr, Hf, Ge, and Sn, with Ti or Ge being essential; and symbol A<1> is one or two or more of alkali metals selected from Li, Na, K, Rb, and Cs, with at least one of Na, Rb, and Cs being essential), wherein the red fluorescent substance has an emission spectrum having a peak between 600 to 650 nm, a fluorescent life time up to 5.0 milliseconds at room temperature, and an internal quantumefficiency at least 0.60 at the time of excitation at 450 nm. Because of the short fluorescent life time, high emission intensity, and high emission efficiency, the red fluorescent substance is suitable for use in the display device that needs high-speed high-definition rendering.

The invention discloses a partial zinc blende activated complex copper-lead-zinc sulfide ore differential flotation separation method. The method comprises the steps that by adding a flotation rate regulator and a pH regulator, the flotation rate of copper pyrites and non-activated zinc blende is lowered, the activated zinc blende flotation rate is increased, and bulk concentrate adopting the activated zinc blende as the main component is obtained through differential flotation; on the basis of the flotation rate regulator and the pH regulator, the flotation rate difference between the copperpyrites and the non-activated zinc blende is increased, high-grade copper concentrate is obtained through flotation separation preferentially, and zinc blende and a small amount of galena can continueto be recycled in nonfloat. The method achieves mineral individuation and differential flotation separation, high-grade copper concentrate can be obtained, meanwhile, the comprehensive recycling rateof copper zinc in sample ore is increased, the flow technology is easy to implement, the economic benefits are remarkable, and comprehensive recycling of hard-dressing complex copper-lead-zinc sulfide ore resources is effectively achieved.

The purpose of the present invention is to provide organometallic salt compositions that are useful as lubricant additives and / or in lubricant additive compositions to reduce friction and wear, and also have improved solubility in all four types of hydrocarbon base oils (Groups I-IV) at a variety of concentrations and under a variety of conditions. The organometallic salt composition is derived from at least one long chain monocarboxylic acid and a single metal in combination with at least one short or medium branched-chain monocarboxylic acid. The compositions are particularly useful in combination with activated complexes comprising a first metal component, a second metal component and particles comprising the first metal component.

A coated phosphor comprises phosphor particles, wherein said phosphor particles comprise manganese-activated complex fluoride phosphors; and a coating on individual ones of said phosphor particles, said coating comprising a layer of carboxylic acid material encapsulating the individual phosphor particles.

The invention aims to an antimicrobial environment-friendly transparent nitro bright finish coat and a preparation method thereof. The finish coat is prepared from a main paint and a diluter in a weight ratio of 1:(0.5-1); and the main paint is prepared from the following raw materials in parts by weight: 10-30 parts of synthetic fatty acid resin, 5-10 parts of aldehyde ketone resin solution with the solid content of 60-80%, 40-60 parts of nitrocellulose, 3-5 parts of environment-friendly plasticizer, 0.1-1 part of defoaming agent, 0.5-2 parts of leveling agent, 0.2-1 part of wetting agent, 0.2-0.5 part of ultraviolet absorbent, 0.2-0.5 part of antioxidant, 0.5-1 part of high-oxidation-state nano silver ion solution and 10-20 parts of environment-friendly mixed solvent. The finish coat can form a non-toxic harmless high-oxidation-state activated complex silver ion bactericidal coating on the film surface, thereby effectively killing the harmful bacteria and protecting the good health. The finish coat has the advantages of excellent yellowing resistance, high bactericidal efficiency and long duration time.

The invention discloses a preparing method of a porous metal organic frame with the small organic molecule fluorescent recognition function. The preparing method includes the following steps that 1, an organic ligand 5-(4-pyridine-4-yl-benzamido)-isophthalic acid (H2PYBI) is synthesized; 2, a Zn-MOF material is synthesized, wherein Zn(NO3)2.6H2O and H2PYBI are weighed, dissolved in solvent, heated in a reaction kettle for reaction and cooled to the room temperature after reaction is finished to obtain the Zn-MOF material; 3, activated complex is prepared, wherein the Zn-MOF material in the heating step 2 to remove guest molecules so as to obtain the activated complex. Compared with the prior art, the porous metal organic frame with the small organic molecule fluorescent recognition function has the structural advantages of high porosity, large specific surface area, regular pore passages and an adjustable skeleton, is high in heat stability and chemical stability and can be directly prepared into a device for detecting nitrobenzene.

The present invention pertains to the following: a phosphor in which humidity resistance is improved by modifying the particle surface of an Mn4+ activated complex fluoride phosphor which can achieve high luminance red-color light emission; and a light emitting element and a light emitting device which excel in color rendering properties and in stability as a result of using such phosphor. This phosphor is represented by general formula A2MF6:Mn4+. Element A is an alkali metal element containing at least K. Element M is at least one type of metal element selected from among Si, Ge, Sn, Ti, Zr, and Hf. F is fluorine and Mn is manganese. The phosphor is characterized in that the particle surface thereof is modified so that the content of fluorine in a supernatant liquid is no more than 2 wt%, the supernatant liquid being obtained after dispersing fluorine in a methanol water mixture (with a water content of 10 mass%) of 100 parts by mass ratio and leaving the same to stand for 10 minutes.

The present invention relates to an Mn4|-activated complex fluoride phosphor with improved moisture resistance due to modification of the particle surface, and a light emitting element and light emitting device having excellent color rendering properties and stability due to the use of this phosphor.The phosphor of the present invention is characterized in that it is represented by the general formula: A2MF6:Mn4−, wherein element A is an alkali metal element comprising at least K, element M is one or more metal elements chosen from among Si, Ge, Sn, Ti, Zr and Hf, F is fluorine, and Mn is manganese, wherein the phosphor comprises a Ca-containing compound on a particle surface.

Compositions, methods, and processes are used in topical applications for human or animal skin. A combination of five (5) active ingredients: caffeine, trehalose, asparagus extract, ceramide 2 (2%) and a resurrection plant, Myrothamnus flabellifolia, extract are used in a topical formulation, such as a cream, lotion, spray or gel to boost or activate autophagy, the body's innate processes for repairing cell damage. The five active ingredients are combined in different formulations to provide at least six (6) products for topical application, including, but not limited to, a cleanser, a spray essence, a day cream, a night cream, a serum and a booster. The five (5) active ingredients provide a unique biological composition, hereinafter called, “autophagy activating complex,” that changes the way skin ages, restores and renews radiance.

The invention relates to the field of honeybee culture, and concretely discloses a swarm spring-breeding fermentation feed. The feed takes artificially prepared substituted pollen feed, cane sugar and water as the raw materials, the artificially prepared substituted pollen feed, cane sugar and the water are mixed according to the proportion being 2: 1: 1, a syrup activated complex formulation bacterial strain is added, the materials are uniformly mixed, a mixture is placed in a special fermentation bag, the fermentation bag is sealed and exhausted, then the fermentation is carried out at the temperature of 20-35 DEG C, the fermentation time is negatively relative to the temperature, and the fermentation time is controlled in 3-10 days. The nutrient determination and swarm breeding test prove that the fermentation feed can satisfy the swarm spring-breeding nutrition requirement, the honeybees love to eat the feed, and the breeding effect is better. The feed solves the problems of poor palatability, anti-nutrition factor containing, low appetite and large waste of the common substituted pollen feeds, and has the advantages of low cost, simple fermentation technology, easy acquisition of the bacterial strain, safety and health.

The present invention relates to an Mn4+-activated complex fluoride phosphor with improved moisture resistance due to modification of the particle surface, and a light emitting element and light emitting device having excellent color rendering properties and stability due to the use of this phosphor.The phosphor of the present invention is characterized in that it is represented by the general formula: A2MF6:Mn4+, wherein element A is an alkali metal element comprising at least K, element M is one or more metal elements chosen from among Si, Ge, Sn, Ti, Zr and Hf, F is fluorine, and Mn is manganese, wherein the phosphor comprises Ca in a concentration range of at least 20 ppm and at most 10,000 ppm or Cl in a concentration range of at least 20 ppm and at most 300 ppm.

A red fluorescent substance includes an Mn-activated complex fluoride represented by the formula (1) below:A12MF6:Mn  (1)(wherein, letter M is one or two or more of tetravalent elements selected from Si, Ti, Zr, Hf, Ge, and Sn, with Ti or Ge being essential; and symbol A1 is one or two or more of alkali metals selected from Li, Na, K, Rb, and Cs, with at least one of Na, Rb, and Cs being essential). The red fluorescent substance has an emission spectrum having a peak between 600 to 650 nm, a fluorescent life time up to 5.0 milliseconds at room temperature, and an internal quantum efficiency at least 0.60 at the time of excitation at 450 nm.Because of the short fluorescent life time, high emission intensity, and high emission efficiency, the red fluorescent substance is suitable for use in the display device that needs high-speed high-definition rendering.

Provided is a method for producing a red phosphor which is a Mn-activated complex fluoride represented by formula (1), A2MF6:Mn (1) (M is one type or more of a tetravalent element selected from Si, Ti, Zr, Hf, Ge, and Sn, and A is one type or more of an alkali metal selected from Li, Na, K, Rb, and Cs, and includes at least Na and / or K.), wherein, as a reactive source, a solid of a complex fluoride represented by formula (2), A2MF6 (2) (M and A are as described above) and a solid of a manganese compound represented by formula (3), A2MnF6 (3) (A is as described above) are mixed and heated at a temperature of from 100° C. to 500° C. According to the present invention, a Mn-activated complex fluoride phosphor having favorable luminescence properties can be obtained without using hydrofluoric acid in a main step.

The purpose of the present invention is to provide organometallic salt compositions that are useful as lubricant additives and / or in lubricant additive compositions to reduce friction and wear, and also have improved solubility in all four types of hydrocarbon base oils (Groups I-IV) at a variety of concentrations and under a variety of conditions. The organometallic salt composition is derived from at least one long chain monocarboxylic acid and a single metal in combination with at least one short or medium branched-chain monocarboxylic acid. The compositions are particularly useful in combination with activated complexes comprising a first metal component, a second metal component and particles comprising the first metal component.

The invention discloses a partial zinc blende activated complex copper-lead-zinc sulfide ore differential flotation separation method. The method comprises the steps that by adding a flotation rate regulator and a pH regulator, the flotation rate of copper pyrites and non-activated zinc blende is lowered, the activated zinc blende flotation rate is increased, and bulk concentrate adopting the activated zinc blende as the main component is obtained through differential flotation; on the basis of the flotation rate regulator and the pH regulator, the flotation rate difference between the copperpyrites and the non-activated zinc blende is increased, high-grade copper concentrate is obtained through flotation separation preferentially, and zinc blende and a small amount of galena can continueto be recycled in nonfloat. The method achieves mineral individuation and differential flotation separation, high-grade copper concentrate can be obtained, meanwhile, the comprehensive recycling rateof copper zinc in sample ore is increased, the flow technology is easy to implement, the economic benefits are remarkable, and comprehensive recycling of hard-dressing complex copper-lead-zinc sulfide ore resources is effectively achieved.

A coated phosphor comprises phosphor particles, wherein said phosphor particles comprise manganese-activated complex fluoride phosphors; and a coating on individual ones of said phosphor particles, said coating comprising a layer of carboxylic acid material encapsulating the individual phosphor particles.

Provided is a method of producing a Mn-activated complex fluoride phosphor, the method including: mixing a red phosphor as a Mn-activated complex fluoride represented by the following formula (1):K2MF6:Mn  (1)wherein M is one or two or more of tetravalent elements selected from the group consisting of Si, Ti, Zr, Hf, Ge and Sn and necessarily includes Si, with K2MnF6 in solid state and optionally with a hydrogenfluoride represented by the following formula (2):AF.nHF  (2)wherein A is one or two or more of alkali metals and / or ammonium selected from the group consisting of Li, Na, K, Rb and NH4 and necessarily includes K, and n is a number of 0.7 to 4, in solid state; and heating the resulting mixture at a temperature of 100 to 500° C.According to the present invention, it is possible to obtain a Mn-activated complex fluoride phosphor which can be used with smaller amount as compared to those according to the related art.

The invention provides a fluorescent material for white-light LEDs and a manufacturing method thereof. According to the fluorescent material, excitation light sources within the range of ultraviolet to green ray are excitable and rare earth Eu ions are used as a main activator. The material has illuminant color from blue system to red system. The composition of the fluorescent material is MxA delta ByOzC gamma: eta Eu, zeta D / omega T. The material is characterized in that the material is a multiphase structure composed of a rare earth ion-activated silicate or phosphate or borate fluorescent solid solution phase and one or more elements of inert metal particles such as Au, Ag, Pt and Pd. With the presence of the inert metal particles in the multiphase structure, luminescence property of the fluorescent solid solution phase can be improved obviously. After excited by ultraviolet-blue green light within the emission peak wavelengths of 300-500 nm, luminescent spectrum with one or more peaks within the peak wavelengths of 450-600 nm can be emitted, and luminescence from blue to orange red can be shown. The multiphase fluorescent material is applied in manufacturing of LED devices.

The present invention relates to an Mn4+-activated complex fluoride phosphor with improved moisture resistance due to modification of the particle surface, and a light emitting element and light emitting device having excellent color rendering properties and stability due to the use of this phosphor.The phosphor of the present invention is characterized in that it is represented by the general formula: A2MF6:Mn4+, wherein element A is an alkali metal element comprising at least K, element M is one or more metal elements chosen from among Si, Ge, Sn, Ti, Zr and Hf, F is fluorine, and Mn is manganese, wherein the phosphor comprises a Ca-containing compound on a particle surface.

The invention discloses a method for preparing a porous metal-organic framework with a fluorescent recognition function for small organic molecules, comprising the following steps: (1) synthesizing an organic ligand 5-(4-pyridin-4-yl-benzamido) ‑isophthalic acid (H2PYBI); (2) Synthesis of Zn‑MOF material: after weighing Zn(NO3)2 6H2O and H2PYBI and dissolving them in a solvent, heat the reaction in a reactor, and cool down to room temperature after the reaction, to obtain Zn-MOF material; (3) preparing an activated complex: heating the Zn-MOF material in step (2) to remove guest molecules to obtain an activated complex. Compared with the prior art, the porous metal-organic framework with fluorescence recognition function for small organic molecules of the present invention has structural characteristics such as high porosity, large specific surface area, regular pores, and adjustable skeleton size, and is thermally and chemically stable. Well, it can be directly prepared as a device to detect nitrobenzene.