37 results about "2,6-Dimethylnaphthalene" patented technology

The invention discloses a method for preparing 2,6-dimethyl naphthalene by alkylation reaction of MgAPO-11 molecular sieve catalytic naphthalene. The method comprises the following steps of: I, activating an MgAPO-11 molecular sieve; and II, mixing naphthalene with an alkylation reagent and a solvent to prepare a feed solution, and carrying out alkylation reaction on the feed solution and the activated MgAPO-11 molecular sieve catalytic naphthalene to obtain the 2,6-dimethyl naphthalene. According to the method for preparing 2,6-dimethyl naphthalene by alkylation reaction of MgAPO-11 molecular sieve catalytic naphthalene, the used MgAPO-11 molecular sieve is synthesized by adopting a conventional electric heating method or a microwave heating method; the alkylation reaction of the MgAPO-11 molecular sieve catalytic naphthalene can be used for overcoming the defects that the homogeneous catalysts including anhydrous AlCl3 and the like are difficult to separate from the product, severe in device corrosion and severe in environment pollution, so that the reaction activity and 2,6-DMN (Dimethylnitrosamine) selectivity are higher, the 2,6- / 2,7-DMN ratio and anti-carbon deposition capacity are higher. Moreover, the reaction products and the catalysts are easy to separate. Besides, the method is simple to operate and convenient for large-scale production.

The invention provides a method for preparing 2,6-dimethylnaphthalene by catalyzing naphthalene alkylation reaction with CoAPO-11 molecular sieve, relates to a method for preparing 2,6-dimethylnaphthalene, and is used for solving the problems that the traditional catalyst cannot simultaneously have high activity and high selectivity of 2,6-dimethylnaphthalene. The method comprises the steps of: activating the CoAPO-11 molecular sieve synthesized by an electrical heating method or microwave heating method for 2h, then mixing with naphthalene, alkylation reagents and solvent to prepare raw material liquid, and carrying out alkylation reaction to obtain 2,6-dimethylnaphthalene. According to the invention, the synthesized CoAPO-11 molecular sieve has higher catalytic reaction activity on naphthalene alkylation reaction, and higher selectivity of 2,6-dimethylnaphthalene; and the method is suitable for preparing 2,6-dimethylnaphthalene.

The ionic liquid catalyzed transalkylation process for preparing 2, 6-dimethyl naphthalene includes: mixing 2-methyl naphthalene or mixed methyl naphthalene, transalkylating agent and solvent in the molar ratio of 1 to (0.5-3) to 12; adding ionic liquid catalyst in 20-75 % of the total weight of the mixture liquid, and transalkylating reaction at the temperature of 20 deg.c to reflux temperature under the protection of inert gas for 2-11 hr to obtain 2, 6-dimethyl naphthalene. The present invention has simple technological path, reuse of the catalyst, no environmental pollution, greatly raised 2, 6-dimethyl naphthalene selectivity and lowered production cost.

Provided are a novel microorganism and a method for purifying 2,6-naphthalene dicarboxylic acid with high purity using the microorganism. The microorganism is Pseudomonas sp. Strain HN-72 isolated from soil and has the ability to convert 2-formyl-6-naphthoic acid contained as an impurity in a crude naphthalene dicarboxylic acid, which is an oxidation product of 2,6-dimethylnaphthalene, to 2,6-naphthalene dicarboxylic acid. The Pseudomonas sp. strain HN-72 has excellent effects in producing high-purity 2,6-naphthalene dicarboxylic acid in high yield.