The invention provides a photovoltaic energy storage charging direct current micro-grid control method, and belongs to the field of direct current micro-grid control. According to the photovoltaic energy storage charging direct current micro-grid control method, direct current busbar voltage is firstly determined, and a control mode of a direct current micro-grid is chosen; in mode 1, a maximum power tracking output mode is adopted in a photovoltaic battery, a constant voltage mode is adopted in an energy storage battery to control the busbar voltage, and a super-fast-charge / fast-charge mode is adopted in an electric automobile; in mode 2, a constant voltage mode is adopted in the photovoltaic battery to control the busbar voltage, a current limiting charging mode is adopted in the energystorage battery, and the super-fast-charge / fast-charge mode is adopted in the electric automobile; in mode 3, the maximum power tracking output mode is adopted in the photovoltaic battery, a current limiting constant voltage mode is adopted in the energy storage battery to control the busbar voltage, and a slow charging mode is adopted in charging of the electric automobile; and in mode 4, the state of the photovoltaic battery and the state of the energy storage battery are the same with the mode 3, and a blocking mode is adopted in charging of the electric automobile. According to the photovoltaic energy storage charging direct current micro-grid control method, the busbar voltage can be controlled in all sorts of situations, and stable operation of a photovoltaic energy storage chargingdirect current micro-grid is guaranteed.