The invention discloses an in-situ preparation method and application of an amido composite
solid electrolyte. An
isocyanate derivative, a small-molecular-weight hydroxyl organic
monomer, high-molecular
polyethylene oxide (PEO), a
lithium salt and a
surface film-forming additive are used as main raw materials, dissolved in a
solvent, stirred and mixed, and uniform
slurry is obtained; then the surface of a positive
electrode material of the
solid battery is coated with the mixed
slurry to form a
slurry film; and the positive
electrode material coated with the slurry film is heated until the slurry film is cured into a
solid film to obtain the amido composite solid
electrolyte tightly combined with the surface of the positive
electrode material. The prepared amino composite solid
electrolyte film is combined with the surface of a solid battery positive
electrode material, a secondary
lithium ion solid battery is obtained through assembling, and the secondary
lithium ion solid battery is suitable for the conditions that the working potential is larger than or equal to 4.3 V vs.Li<+> / Li, and the
working temperature is not higher than 40 DEG C. The method disclosed by the invention is relatively simple in process, and the problem of
decomposition of PEO in the high-
voltage battery can be fundamentally solved, so that the stable performance of the battery is improved.