The invention belongs to the technical field of the express deliver industry, and particularly relates to an express deliver order scrambling system and an express deliver order scrambling method. The express deliver order scrambling system comprises a client mobile terminal, a courier mobile terminal, a database server and an application server, wherein the client mobile terminal and the courier mobile terminal are both connected with the application server through wireless transmission; the database server is connected with the application server. By adopting the express deliver order scrambling system and the express deliver order scrambling method, for express deliver companies, couriers can pick up express parcels on the way, so that the on-road time is shortened, the efficiency is improved, and particularly for small-size express delivery companies, a window for demonstrating self capability is available, and the competitiveness is improved; for clients, orders can be made relatively and conveniently, that is, orders can be made by self through WeChat, the time waste caused by the situation that the telephone of an express delivery company cannot be got through is reduced, and the time for waiting for couriers to pick up the parcels can be shortened for the clients.