133 results about "Fluorophosphate glass" patented technology

Provided are near-infrared light-absorbing glass in which good color compensating characteristics are maintained even without containing harmful arsenic, permitting the thinning of the glass, and having good weatherability and forming properties; a near-infrared light-absorbing element comprised of such glass; a near-infrared light-absorbing filter employing such glass. Also provided, at low cost, are near-infrared light-absorbing glass permitting good color compensating, a near-infrared light-absorbing element comprised of such glass, and a near-infrared light-absorbing filter comprising such elements. The glass comprises cationic components with a certain composition as well as F<-> and O<2-> as anionic components. Alternatively, the glass is near-infrared light-absorbing glass, wherein the glass exhibits properties, based on a thickness of 0.5 mm, in the spectral transmittance of wavelengths of 400 to 700 nm, that wavelength, at which a 50 percent transmittance is exhibited, is less than 630 nm, transmittance at a wavelength longer than said wavelength is less than 50 percent, transmittance at a wavelength shorter than said wavelength is higher than 50 percent and the viscosity at a liquid phase temperature is 0.5 Pa.s or more. The near-infrared light-absorbing element is comprised of such glass. The near-infrared light-absorbing filter comprises a glass plate comprised of such glass. Alternatively, the glass is comprised of fluorophosphate glass or phosphate glass, and comprises 0.1 weight percent or more of copper based on CuO, 0.005 to 0.5 weight percent of iron based on Fe2O3, 0.01 to 1 weight percent of antimony based on Sb2O3, and no arsenic.

Provided are an optical glass having high-refractivity, low-dispersion and anomalous partial dispersion properties, having excellent processability, being excellent as an anomalous partial dispersion glass for suppressing chromatic aberration, containing P5+, Al3+ and alkaline earth metal ions selected from the group consisting of Mg2+, Ca2+, Sr2+ and Ba2+ as essential cationic components and F- and O2- as essential anionic components, wherein the ratio of content of Ba2+ to the total content R2+ of Mg2+, Ca2+, Sr2+ and Ba2+, Ba2+ / R2+, is 0.01 or more but less than 0.5 on the basis of cationic %, and having an Abbe's number (nud) of 68 or more, optical glass having an Abbe's number (nud) of 68 or more, a partial dispersion ratio of 0.535 or more and a frictional abrasion of 500 or less and an optical glass which is to be polished in a polishing step for producing an optical element and which is a fluorophosphate glass having a frictional abrasion of 500 or less.

The present invention provides a fluorophosphate glass containing 30 to 50 cationic % of a phosphorus ingredient in terms of P5+, the glass having, in a nuclear magnetic resonance spectrum, a resonance spectrum which is generated near a reference frequency of 31P and has a shape of Gaussian function. The glass of the invention is reduced in volatility and erosiveness.

A fluorophosphate glass containing: P5+ in an amount of 20 to 45 cationic %; Al3+ in an amount of 15 to 35 cationic %; Ba2+ in an amount of 20 to 50 cationic %; F− in an amount of 20 to 50 anionic %; and O2− in an amount of 50 to 80 anionic %. A molar ratio of O2− / P5+ is larger than or equal to 3.5. In addition, a molar ratio of Al3+ / P5+ is larger than or equal to 0.45. Furthermore, the Abbe number (νd) of the glass is larger than or equal to 66. Finally a refractive index (nd) of the glass satisfies an expression (1): nd≧2.0614−0.0071×νd.

New and improved compositions of doped and co-doped bismuth fluorophosphate glasses for lasers is disclosed that have a high refractive index (nD) of approximately 1.6 and higher, high transmission in the near infrared part of the spectrum, and a wide glass forming domain. The disclosed glass systems Al(PO3)3-Ba(PO3)2-Bi(PO3)3-BaF2+RFx+dopands use dopants from the group of oxides and or fluorides of rare earth elements Nd, Er, Yb, Tm, Tb, Ho, Sm, Eu and Pr as well as MnO and mixtures thereof over 100 percent (wt %) of the glass-base composition. These glasses have high chemical durability, radiation resistance, efficiency of laser use in the infrared and blue spectrum, and improved duration of luminescence.

New and improved compositions of doped and co-doped bismuth fluorophosphate glasses for lasers is disclosed that have a high refractive index (nD) of approximately 1.6 and higher, high transmission in the near infrared part of the spectrum, and a wide glass forming domain. The disclosed glass systems Al(PO3)3−BA (PO3)2−Bi(PO3)3−BaF2+RFx+dopands use dopants from the group of oxides and or fluorides of rare earth elements Nd, Er, Yb, Tm, Tb, Ho, Sm, Eu and Pr as well as MnO and mixtures thereof over 100 percent (wt %) of the glass-base composition. These glasses have high chemical durability, radiation resistance, efficiency of laser use in the infrared and blue spectrum, and improved duration of luminescence.

New and improved compositions of doped fluorophosphate glasses for lasers have a high refractive index (nD) of approximately 1.6 to 1.7, high transmission in the near infrared part of the spectrum and a wide glass forming domain. These glass systems, Ba(PO3)2—Al(PO3)3—BaF2-Dopants, utilize dopants from the group of: oxides or fluorides of the rare earth elements: Sm, Eu, Nd, Er, Yb, Tm, Tb, Ho and Pr: as well as MnO; and mixtures thereof. The composition of glass includes chemical durability, efficiency of laser use in the infrared spectrum and improved duration of luminescence. It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

The invnetion provides fluoroposphate glass, precision press molding preform, optical element blank, optical element and method of manufacturing the same. A fluorophosphate glass of the invention contains more than 3 cationic % and 30 cationic % or less of a phosphorus ingredient in terms of P<5+>, the glass having a ratio I(1) / I(0) of equal to or less than 0.08 in which I(0) is a strength of a resonance peak generated near a reference frequency of <31>P in a nuclear magnetic resonance spectrum and I(1) is a strength of a first-order side band peak of the resonance peak. The glass of the invention is reduced in volatility and erosiveness.

Provided is a low-dispersion optical glass that is formed of a fluorophosphate glass in which the molar ratio of the content of O2− to the content of P5+, O2− / P5+, is 3.5 or more and that has an Abbe's number (νd) of over 70 or has an F− content of 65 anionic % or more, and the optical glass enables the suppression of the volatilization of a glass component when an optical glass formed of a fluorophosphate glass is produced or when an obtained glass in a molten state is caused to flow out to shape it into a glass shaped material, so that the variation of properties such as a refractive index, etc., involved in the fluctuations of a glass composition and the variation of quality such as the occurrence of striae can be suppressed.

The present invention provides a fluorophosphate glass containing phosphorus, oxygen and fluorine as glass ingredients, in which, provided that a refractive index nd of the glass is nd(1) and a refractive index nd after re-melting the glass at 900 DEG C for 1 hour in a nitrogen atmosphere, cooling the glass to a glass transition temperature and then cooling the glass down to 25 DEG C at a temperature decrease rate of 30 DEG C per hour is nd<(2)>, an absolute value of a difference between nd<(1)> and nd<(2)> (nd<(2)>-nd<(1)>) is equal to or less than 0.00300, and a molar ratio (O<2-> / P<5+>) of a content of O<2-> to a content of P<5+> is equal to or more than 3.5. The glass of the invention is reduced in volatility and erosiveness.

A host material for Tm<3+>-doping is provided. The host material is a fluorophosphate glass having a non-zero concentration of Tm<3+>, cation elements that include at least an alkaline earth, phosphorus, and aluminum, and anion elements that include oxygen (O) and fluorine (F). The fluorine(F) / oxygen (O) ratio (F / (F+O)) for the fluorophosphate glass of the embodiments of the present invention can be in the range of about 0.5 to about 0.85. The fluorophosphate glass further can have an alkali metal concentration of 10 mole % or less to improve durability. The Tm-doped fluorophosphate glass can be incorporated into an amplifier or laser utilized in the 14xx nm wavelength region.

Provided is an inexpensive near infrared cut-off filter which, by being provided with a thin-film attenuation layer that effectively blocks a rays emitted from substrate glass and that is in a form so as to not influence optical characteristics, can even be used as cover glass for a solid state imaging sensor package. The thin-film attenuation layer for attenuating a rays emitted from substrate glass is formed on at least one light-permeable surface of substrate glass produced from fluorophosphate glass containing CuO or phosphate glass containing CuO.