The invention relates to the technical field of rubber, in particular to a tire sidewall rubber combination comprising 1,2-syndiotactic polybutadiene. 100 weight parts of rubber components serve as the standard, and the combination further includes, by weight, 35-65 parts of carbon black, 5-25 parts of environmentally-friendly aromatic oil, 1.0-5.0 parts of tackifying resin, 1.0-4.0 parts of zinc oxide, 0.5-2.5 parts of stearic acid, 1.5-3.5 parts of sulphur and 0.5-3.0 parts of accelerant. The rubber components include, by weight, 5-50 parts of polybutadiene rubber, 5-45 parts of 1,2 syndiotactic polybutadiene and 35-55 parts of natural rubber. According to the tire sidewall rubber combination comprising the 1,2-syndiotactic polybutadiene, the tire running noise is effectively lowered, the driving comfort is improved, the rolling resistance of a tire is relieved, the physical and mechanical performances of tires made of the tire sidewall rubber combination are basically identical with those of common tires, and the advantages of the wet land griping force and the dry land controllability of the tires are maintained.