Inflatable tire
A technology for pneumatic tires and treads, applied in special tires, tire parts, rolling resistance optimization, etc., can solve the problems of not considering deformation, not considering the inhibition of deformation of the bottom of the main groove, etc., and achieve the effect of good rolling resistance
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[0132] Although the present invention has been described in detail with reference to examples, the present invention is not limited thereto.
[0133] Various chemicals used in Examples and Comparative Examples are explained below.
[0134] High cis BR: CB 25 (manufactured by Lanxess AG, high cis BR obtained by using Nd catalyst, Mooney viscosity ML l+4 : 44, Mw / Mn: 1.78, Mw: 500,000, Mn: 280,000, cis-1,4 bond content ratio: 96.2 mass%, trans-1,4 bond content ratio: 3.1 mass%, vinyl content: 0.7 quality%)
[0135] Modified BR: BR1250H (manufactured by Zeon Co., polymerized by using lithium as an initiator, vinyl bond content: 10 to 13% by mass, Mw / Mn: 1.5, tin atom content: 250ppm)
[0136] BR containing SPB: VCR617 (manufactured by Ube Industries, Ltd., suspension of 1,2-syndiotactic polybutadiene crystals, melting point of 1,2-syndiotactic polybutadiene crystals: 200°C, boiling The n-hexane insoluble matter content: 15-18% by mass, 1,2-syndiotactic polybutadiene crystal co...
preparation example A1~A28
[0163] Preparation Examples A1 to A28 (Rubber Compositions for Cap Treads)
[0164] Using various chemicals as shown in Tables 1 to 3, a kneading process X in which the rubber component, carbon black total volume, and silica half volume were kneaded (extrusion temperature: 150° C., 4 minutes) was performed; A kneading process Y in which chemicals other than the vulcanizing agent (sulfur, vulcanization accelerator, crosslinking agent) are mixed with the compound obtained in the kneading process X and kneaded (extrusion temperature: 150°C, 3 minutes); and further A kneading process F of mixing a vulcanizing agent and kneading (extrusion temperature: 100° C., 3 minutes) to obtain an unvulcanized rubber composition for a cap tread. Here, in the case of using a mercapto silane coupling agent (silane coupling agents 2 and 3), the kneading temperature in the kneading process X and the kneading process Y was changed to 140° C. to prevent scorching of the rubber. produce.
preparation example B1~B6
[0165] Production Examples B1 to B6 (Rubber Compositions for Base Treads)
[0166] Using various chemicals as shown in Table 4, a kneading process X in which chemicals other than the vulcanizing agent (sulfur, vulcanization accelerator, crosslinking agent) were kneaded (extrusion temperature: 150° C., 4 minutes) was performed; And a kneading process F was performed in which a vulcanizing agent was further mixed and kneaded (extrusion temperature: 100° C., three minutes), thereby obtaining an unvulcanized rubber composition for a base tread.
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