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Silicon wafer cleaner and silicon wafer cleaning method

A silicon wafer cleaning agent and a technology for cleaning silicon wafers, applied in detergent compositions, detergent compounding agents, chemical instruments and methods, etc., can solve the problems of easy decomposition of hydrogen peroxide, process influence, and incomplete cleaning effect, and achieve no Effects of irritating odor, lower production cost, good decontamination effect

Inactive Publication Date: 2016-04-20
UNIV OF ELECTRONICS SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Rough polishing uses a higher concentration of sodium hydroxide solution to react with silicon wafers. Although the surface damage layer can be removed and surface pollutants can be removed to a certain extent, after rough polishing, the surface solution of silicon wafers remains more alkali, and the amount of thinning is very small. Large, difficult to control, and have a great impact on subsequent processes
The APM cleaning process uses ammonia and hydrogen peroxide for cleaning, and removes slight organic matter, surface particles and some metal pollutants through oxidation and micro-etching. Ammonia is easy to volatilize, hydrogen peroxide is easy to decompose, and needs to be continuously added. The process stability is poor and the cleaning effect is not good. completely

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0011] (1), preparation of silicon wafer cleaning solution:

[0012] Get a 5L glass beaker, add surfactant, organic cleaning agent and deionized water to prepare cleaning agent according to the present invention; wherein, the mass percentage of Tween 80 is 1.5%, the mass percentage of Span 80 is 0.6%, the mass percentage of limonene The percentage is 10% to 30%, the mass percentage of isopropanol is 3% to 10%, and the mass percentage of ethylenediamine is 0.5%. Add deionized water to 4L of the solution, and vigorously stir to form an emulsion to obtain a cleaning agent. Add 80L of deionized water to the pre-cleaning tank, add 4L of the prepared cleaning agent and mix well to obtain a cleaning solution.

[0013] (2) Silicon wafer surface cleaning:

[0014] At room temperature, add 400pcs of silicon wafers into the cleaning solution for cleaning for 4 minutes, and then put them into deionized water for rinsing. After every 15 batches of cleaning, the cleaning solution is replen...

Embodiment 2

[0018] (1) Preparation of silicon wafer cleaning solution:

[0019] Take a 5L glass beaker, add surfactant, organic cleaning agent and deionized water to prepare cleaning agent according to the present invention; wherein Tween 20 mass percent is 1.5%, Span 80 mass percent is 0.8%, limonene mass percent is 40% ~60%, the mass percentage of isopropanol is 10%~15%, ethylenediamine 1%, add deionized water to a solution of 4 liters, stir vigorously to form an emulsion, and form a cleaning agent. Add 80L of deionized water to the pre-cleaning tank, add 4L of the prepared cleaning agent and mix evenly to obtain a cleaning solution.

[0020] (2) Silicon wafer surface cleaning:

[0021] At room temperature, add 400pcs of silicon wafers into the cleaning solution for cleaning for 4 minutes, and then put them into deionized water for rinsing. After every 15 batches of cleaning, the cleaning solution is replenished, and the additional cleaning agent is the original silicon chip cleaning s...

Embodiment 3

[0025] (1) Preparation of silicon wafer cleaning solution:

[0026] Get a 5L glass beaker, add surfactant, organic cleaning agent and deionized water to prepare cleaning agent according to the present invention; wherein Tween 20 mass percent is 1.5%, Span 20 mass percent is 1.5%, limonene mass percent is 60% ~70%, the mass percentage of isopropanol is 15%~20%, ethylenediamine 2%, add deionized water to 4L of the solution, and vigorously stir to form an emulsion to obtain a cleaning agent. Add 80L of deionized water to the pre-cleaning tank, add 4L of the prepared cleaning agent and mix evenly to obtain a cleaning solution.

[0027] (2) Silicon wafer surface cleaning:

[0028] At room temperature, add 400pcs of silicon wafers into the cleaning solution for cleaning for 4 minutes, and then put them into deionized water for rinsing. After every 15 batches of cleaning, the cleaning solution is replenished, and the additional cleaning agent is the original silicon chip cleaning so...

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PUM

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Abstract

The invention provides a silicon wafer cleaner and a silicon wafer cleaning method, which are used for manufacturing of silicon solar cells, and belongs to the technical field of solar cell production. The cleaner is a mixed solution of a surfactant prepared from a tween series and a span series as well as an organic cleanser and deionized water, wherein the organic cleanser comprises limonene, isopropanol and ethylenediamine. The cleaning method comprises steps as follows: components of the cleanser are uniformly mixed, deionized water which is 20-25 times of the components is added for dilution, and a silicon wafer is put in a cleaning fluid at the normal temperature for cleaning. The method is particularly applicable to cleaning of a silicon wafer with a dirty surface; a rough polishing and APM (advanced power management) process is replaced with the method, the use amount of ammonia water and hydrogen peroxide can be effectively reduced, and no corrosion is caused to the surface of the silicon wafer; requirements for equipment are low, the operation is simple, the production cost can be greatly reduced, and the current production concept of high efficiency and environmental protection is met.

Description

technical field [0001] The invention relates to a silicon chip cleaning agent and a silicon chip cleaning method, which are used for making silicon solar cells and belong to the technical field of solar cell production. Background technique [0002] In the production of monocrystalline silicon solar cells, the general production and processing process of silicon wafers is single crystal growth→cutting→outer diameter barrel grinding→flat edge or V-shaped groove processingslicing→chamfering→grinding, corrosionpolishing→cleaning→inspection →Surface texturing and picklingdiffusion junction→phosphorous silicon glass→plasma etching and pickling→anti-reflection coatingscreen printing→rapid sintering, etc. The above-mentioned cleaning mainly refers to the final cleaning after polishing, and many steps in the processing of single crystal silicon wafers need to be cleaned. Generally, there is a cleaning process before the end of each process to eliminate the pollutants in this pro...

Claims

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Application Information

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IPC IPC(8): C11D10/02H01L21/02
CPCC11D3/188C11D1/667C11D1/825C11D3/2017C11D3/30H01L21/02068
Inventor 张震华吴孟强其他发明人请求不公开姓名
Owner UNIV OF ELECTRONICS SCI & TECH OF CHINA
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