The invention discloses a dual-phase rectification flue gas desulfurization technology, which comprises a plurality of steps that (1) an absorption tower is arranged, (2) the flue gas is injected, (3) the limestone slurry is pumped in, and (4) the reaction product is collected. The dual-phase rectification flue gas desulfurization technology is characterized in that (1) the nonuniformity of flow field inside the spray tower is utilized, (2) the even rectification of liquidoid and gas phase is not processed on account of the design of rectifying plate and spray layer intentionally, (3) the resistance of flue gas is decreased and the velocity of flow of flue gas is uninfluenced, and (4) the liquidoid and the gas phase are kept turbulent state consistently because of the nonuniformity of liquidoid and gas phase. The dual-phase rectification flue gas desulfurization technology has the advantages of fierce collision, intense reaction, enough absorption, good performance of desulfurization, high efficiency, fast reaction rate, good performance of counter-current reaction, optimization of flow field, low system pressure drop, energy-saving, low device cost and maintenance cost, and direct maintenance and shift of inner parts without building temporary maintenance platform in the process of maintenance of absorption tower inner parts.