The invention discloses a structure of a double-balloon laryngeal mask airway for gastroenterological endoscope examination. The double-balloon laryngeal mask airway comprises a ball balloon, a cover balloon, an air vent pipe, an air source joint, inflation tubes, a plug and pressure indicators, wherein the ball balloon is ball-shaped; the cover balloon is oval-shaped; the air vent pipe sequentially passes through the ball balloon and the cover balloon; a front-end opening of the air vent pipe is wrapped by the ball balloon to form a ring-shaped balloon buffering opening, the middle part of air vent pipe is connected with the cover balloon to form a back balloon, and an opening in the back end of the air vent pipe is connected with the plug; a bypass channel opening in a side wall of the air vent pipe is connected with the air source joint; and the side wall or the rear part of the air vent pipe is connected with the inflation tubes communicated with the pressure indicators. A gastroenterological endoscope enters the esophagus and the stomach or an intestine of a human body through independent cavity channels at the inner part of the air vent pipe; and a supporting table and a blocking piece are arranged at an air vent opening in the middle part of a laryngeal mask, and the air vent opening is communicated with a trachea of the human body to form a closed respiration channel. Through the adoption of the double-balloon laryngeal mask airway, gastroenterological endoscope examination can be conducted while a patient has an anesthesia operation or is rescued, and reflux content in the stomach can be prevented from entering the trachea, so as to reduce pain of the patient and improve the safety of the operation.