The invention discloses a superconducting material for a negative ion, a reaction film and a negative ion generating device. The superconducting material comprises the following raw materials, by weight: 5 to 10 parts of conductive powder, 10 to 20 parts of electric powder, 10 to 20 parts of negative ion powder, 37 to 70 parts of nano materials, and 10 to 20 parts of carbon crystal powder. According to the invention, the superconducting-material-based reaction film has constant far-infrared absorption and reflection functions and the typical semiconductor characteristic and the absorption bandis mainly located in the far infrared region; the dipole moment changes due to the thermoelectric and piezoelectric effects, so that the powerful reflection capability is realized and the occurrenceof negative ions is also caused. When the external conditions like the temperature, humidity, far-infrared radiation, friction and the like change, an electric field is induced to ionize the air and the knocked electrons are attached to adjacent oxygen molecules, so that the electrons are transformed into small-size negative ions.