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46 results about "Chemiresistor" patented technology

A chemiresistor is a material that changes its electrical resistance in response to changes in the nearby chemical environment. Chemiresistors are a class of chemical sensors that rely on the direct chemical interaction between the sensing material and the analyte. The sensing material and the analyte can interact by covalent bonding, hydrogen bonding, or molecular recognition. Several different materials have chemiresistor properties: metal-oxide semiconductors, some conductive polymers, and nanomaterials like graphene, carbon nanotubes and nanoparticles. Typically these materials are used as partially selective sensors in devices like electronic tongues or electronic noses.

Personal care products with microchemical sensors for odor detection

Absorbent articles comprising one or more sensors capable of detecting the presence of a body waste in the absorbent article are described. In particular, the absorbent articles comprise at least one chemiresistor capable of detecting the presence of volatile organic compounds associated with a body waste. When a body waste is detected, an indicator means signals a caregiver and / or a user of the absorbent article that an insult has occurred
Owner:KIMBERLY-CLARK WORLDWIDE INC

Circular chemiresistors for microchemical sensors

A circular chemiresistor for use in microchemical sensors. A pair of electrodes is fabricated on an electrically insulating substrate. The pattern of electrodes is arranged in a circle-filling geometry, such as a concentric, dual-track spiral design, or a circular interdigitated design. A drop of a chemically sensitive polymer (i.e., chemiresistive ink) is deposited on the insulating substrate on the electrodes, which spreads out into a thin, circular disk contacting the pair of electrodes. This circularly-shaped electrode geometry maximizes the contact area between the pair of electrodes and the polymer deposit, which provides a lower and more stable baseline resistance than with linear-trace designs. The circularly-shaped electrode pattern also serves to minimize batch-to-batch variations in the baseline resistance due to non-uniform distributions of conductive particles in the chemiresistive polymer film.
Owner:SANDIA NAT LAB

Apparatus for sensing volatile organic chemicals in fluids

A chemical-sensing apparatus is formed from the combination of a chemical preconcentrator which sorbs and concentrates particular volatile organic chemicals (VOCs) and one or more chemiresistors that sense the VOCs after the preconcentrator has been triggered to release them in concentrated form. Use of the preconcentrator and chemiresistor(s) in combination allows the VOCs to be detected at lower concentration than would be possible using the chemiresistor(s) alone and further allows measurements to be made in a variety of fluids, including liquids (e.g. groundwater). Additionally, the apparatus provides a new mode of operation for sensing VOCs based on the measurement of decay time constants, and a method for background correction to improve measurement precision.
Owner:NAT TECH & ENG SOLUTIONS OF SANDIA LLC

Methods for characterizing subsurface volatile contaminants using in-situ sensors

An inverse analysis method for characterizing diffusion of vapor from an underground source of volatile contaminant using data taken by an in-situ sensor. The method uses one-dimensional solutions to the diffusion equation in Cartesian, cylindrical, or spherical coordinates for isotropic and homogenous media. If the effective vapor diffusion coefficient is known, then the distance from the source to the in-situ sensor can be estimated by comparing the shape of the predicted time-dependent vapor concentration response curve to the measured response curve. Alternatively, if the source distance is known, then the effective vapor diffusion coefficient can be estimated using the same inverse analysis method. A triangulation technique can be used with multiple sensors to locate the source in two or three dimensions. The in-situ sensor can contain one or more chemiresistor elements housed in a waterproof enclosure with a gas permeable membrane.
Owner:SANDIA NAT LAB

Flexible multi-moduled nanoparticle-structured sensor array on polymer substrate and methods for manufacture

A flexible chemiresistor (CR) sensor for sensing a molecule of interest in a fluid (liquid or gas) is provided. The flexible CR sensor comprises a flexible chemiresistor (CR) module. The flexible CR module comprises a flexible substrate such polyethylene terephthalate (PET), polyethylene naphthalate (PEN) or polyimide (PI), and a thin film nanoparticle assembly assembled on the flexible substrate. The thin film nanoparticle assembly comprises metal or metal alloy core, ligand-capped nanoparticles and molecular linkers connecting the nanoparticles. The flexible CR sensor and an intelligent pattern recognition engine can be incorporated in a handheld device that can detect a molecule of interest in a fluid (e.g., a liquid or gas) accurately, rapidly, and without false positives. Any sensing array nanomaterial, pattern recognition, and compact / or electronic hardware can be integrated to achieve a desired detection limit and response speed.
Owner:THE RES FOUND OF STATE UNIV OF NEW YORK

Personal care products with microchemical sensors for odor detection

Absorbent articles comprising one or more sensors capable of detecting the presence of a body waste in the absorbent article are described. In particular, the absorbent articles comprise at least one chemiresistor capable of detecting the presence of volatile organic compounds associated with a body waste. When a body waste is detected, an indicator means signals a caregiver and / or a user of the absorbent article that an insult has occurred.
Owner:KIMBERLY-CLARK WORLDWIDE INC

Multi-pin chemiresistors for microchemical sensors

A multi-pin chemiresistor for use in microchemical sensors. A pair of free-standing, bare wires is supported by an electrically insulating support, and are oriented parallel to each other and spaced closely together. A free-standing film of a chemically sensitive polymer that swells when exposed to vapors of a volatile chemical is formed in-between the pair of closely-spaced wires by capillary action. Similar in construction to a thermocouple, this “chemicouple” is relatively inexpensive and easy to fabricate by dipping the pair of bare wires into a bath of well-mixed chemiresistor ink. Also, a chemiresistor “stick” is formed by dipping an electrically insulating rod with two or more linear or spiral-wrapped electrical traces into the bath of well-mixed chemiresistor ink, which deposits a uniform coating of the chemically sensitive polymer on the rod and the electrical traces. These “sticks” can be easily removed and replaced from a multi-chemiresistor plug.
Owner:SANDIA NAT LAB

Vapor sensor and materials therefor

The present invention relates to a composition for sensor films used for detecting chemical analytes within sensors, such as polymer-absorption chemiresistors (i.e. conductometric sensors). The present invention provides sensor film compositions that have greater temperature stability and sensitivity to chemical analytes, as well as methods of making these sensor films. Sensor film compositions according to the present invention include a crosslinked siloxane polymer comprising a monomer having a hydrocarbon side group with greater than or equal to two carbon atoms and a plurality of conductive particles distributed within the polymer. Alternate preferred embodiments distribute an oil comprising siloxane having at least one side group with greater than or equal to two carbons through a crosslinked siloxane polymer, wherein the oil is distributed through a crosslinked polysiloxane copolymer. Further, conductive particles having a N2 adsorption of between about 8 to about 25 m2 / g provide enhanced sensor film performance.
Owner:THERM O DISC

Chemiresistor for use in conducting electrolyte solution

The present invention provides a chemiresistor-based sensor for measuring the presence or amount of analyte in an electrolyte solution; said chemiresistor comprising (i) a chemiresistor film wherein the impedance of said nanoparticle film changes in the presence of an analyte; and (ii) two electrically conducting electrodes in electrical contact with said nanoparticle film; wherein said electrically conducting electrodes are adapted to be connected to a device for measuring the impedance of said chemiresistor film under a voltage signal and wherein the impedance of the double layer capacitor formed by the two electrically conducting electrodes in the presence of the electrolyte solution, is larger than the impedance of the chemiresistor film either before or after exposure of the chemiresistor film to the analyte. A method of using said chemiresistor-based sensor to measure the presence or amount of analyte is also provided. Further provided is a method of determining the partition coefficient of an analyte using said chemiresistor-based sensor.
Owner:COMMONWEALTH SCI & IND RES ORG

Flexible multi-moduled nanoparticle-structured sensor array on polymer substrate and methods for manufacture

A flexible chemiresistor (CR) sensor for sensing a molecule of interest in a fluid (liquid or gas) is provided. The flexible CR sensor comprises a flexible chemiresistor (CR) module. The flexible CR module comprises a flexible substrate such polyethylene terephthalate (PET), polyethylene naphthalate (PEN) or polyimide (PI), and a thin film nanoparticle assembly assembled on the flexible substrate. The thin film nanoparticle assembly comprises metal or metal alloy core, ligand-capped nanoparticles and molecular linkers connecting the nanoparticles. The flexible CR sensor and an intelligent pattern recognition engine can be incorporated in a handheld device that can detect a molecule of interest in a fluid (e.g., a liquid or gas) accurately, rapidly, and without false positives. Any sensing array nanomaterial, pattern recognition, and compact / or electronic hardware can be integrated to achieve a desired detection limit and response speed.
Owner:THE RES FOUND OF STATE UNIV OF NEW YORK

Nonlinear gold nanocluster chemical vapor sensor

The present invention is a chemiresistor for qualitative and quantitative analysis of chemical species that consists of a very thin film of particles, nanoclusters, deposited on an insulating substrate and contacted by electrodes. The particles have a metallic core, preferably spheroidal, that is less than 5 nm in diameter and surrounded by an monolayer ligand shell ranging in thickness from 0.4 nm to 2 nm. The Coulomb blockade effects upon which the invention operates result in nonlinear current-voltage characteristics which dramatically improves sensitivity with much lower power dissipation. One property of the ligand shell is that its chemical composition can be chosen to be especially receptive to a particular chemical vapor.
Owner:THE UNITED STATES OF AMERICA AS REPRESENTED BY THE SECRETARY OF THE NAVY

Multi-electrode chemiresistor

The invention relates to “solid state” chemiresistor sensors with electric control of the affinity of a chemosensitive material. The configurations of the present invention enable the fast regeneration of the sensor after analyte binding, which therefore increases selectivity. In one embodiment the chemiresistor sensor is implemented as a multi-electrode chemiresistor, comprising 4 electrodes for the separate measurement of the resistance of the chemosensitive material and the contact resistance, and 2 further electrodes to control the redox state of the chemosensitive sensor material, thereby facilitating fast and effective regeneration of the sensor.
Owner:BRANDENBURGISCHE TECHN UNIV COTTBUS SENFTENBERG

Methods of minimizing temperature cross-sensitivity in vapor sensors and compositions therefor

The present invention relates to methods of making compositions for sensor films used for detecting chemical analytes within sensors, such as polymer-absorption chemiresistors (i.e., conductometric sensors). The sensor films have reduced cross-sensitivity to temperature, while maintaining sensitivity to the chemical analytes. The sensor matrix includes components that are associated with a first temperature coefficient of resistance, such as a polymer resin and / or a first conductive particle. The sensor matrix further comprises a second species, preferably a conductive particle, which has a second temperature coefficient of resistance that is opposite to the first temperature coefficient of resistance. The second species has an opposite influence on a resistance response of the sensor from the first species. In this manner, the sensor matrix exhibits a minimized response in resistance to any changes in temperature.
Owner:THERM O DISC

Methods of minimizing temperature cross-sensitivity in vapor sensors and compositions therefor

The present invention relates to methods of making compositions for sensor films used for detecting chemical analytes within sensors, such as polymer-absorption chemiresistors (i.e., conductometric sensors). The sensor films have reduced cross-sensitivity to temperature, while maintaining sensitivity to the chemical analytes. The sensor matrix includes components that are associated with a first temperature coefficient of resistance, such as a polymer resin and / or a first conductive particle. The sensor matrix further comprises a second species, preferably a conductive particle, which has a second temperature coefficient of resistance that is opposite to the first temperature coefficient of resistance. The second species has an opposite influence on a resistance response of the sensor from the first species. In this manner, the sensor matrix exhibits a minimized response in resistance to any changes in temperature.
Owner:THERM O DISC

A mechanochemical polymerization method for preparing graphene/metal oxide composite electrode materials

A mechanochemical polymerization method for preparing graphene / metal oxide composite electrode material features that graphite and metal oxide precursor are adde into a mechanochemical reactor as rawmaterials to obtain graphene / metal oxide composite electrode material by one-step mechanochemical reaction. That graphene / metal oxide composite electrode material is prepared by adding graphite and metal oxide precursor as raw material to a mechanochemical reactor. A metal oxide precursor in that invention is a multifunctional reagent, As that ion intercalation agent, Graphene is prepare by accelerating graphite peel under that action of mechanical force, On the other hand, Graphene / metal oxide composite electrode material are obtained by in-situ formation of metal oxide on that surface of graphene due to simultaneous mechanical chemical reaction of metal salts, so that a plurality of processes such as preparation of graphene, in-situ load metal oxide and the like are completed in one step, and the preparation process is simplified, and the preparation efficiency of graphene / metal oxide composite material is improved.
Owner:SOUTH CENTRAL UNIVERSITY FOR NATIONALITIES +1

Robust chemiresistor sensor

A chemiresistor sensor probe for detecting target analytes. The probe includes a body having a first control surface and a second control surface recessed within the first. A sensor film comprises numerous conductive particles disposed upon the second surface. The film swells upon absorbing one or more analytes for which it has an affinity, thus causing the conductive particles to become more dispersed and increasing the resistance between the particles. The thickness of the film is equal to the distance between the first surface and the second surface, thus permitting the thickness to be controlled by varying the distance between the control surfaces. The robustness of the sensor probe is enhanced by placing a porous or mesh electrode along with, or in place of, a chemical binding agent between the film and the terminals. The robustness is also improved by placing a diode in series with the sensor circuit.
Owner:THERM O DISC

Nanoparticle sensor having a nanofibrous membrane scaffold

Nanoparticle-fibrous membrane composites are provided as tunable interfacial scaffolds for flexible chemical sensors and biosensors by assembling gold nanoparticles (Au NPs) in a fibrous membrane. The gold nanoparticles are functionalized with organic, polymeric and / or biological molecules. The fibrous membranes may include different filter papers, with one example featuring a multilayered fibrous membrane consisting of a cellulose nanofiber (CN) top layer, an electrospun polyacrylonitrile (PAN) nanofibrous midlayer (or alternate material), and a nonwoven polyethylene terephthalate (PET) fibrous support layer, with the nanoparticles provided on the fibrous membranes through interparticle molecular / polymeric linkages and nanoparticle-nanofibrous interactions. Molecular linkers may be employed to tune hydrogen bonding and electrostatic and / or hydrophobic / hydrophilic interactions to provide sensor specificity to gases or liquids. The sensors act as chemiresistor-type sensors. A preferred implementation is a sweat sensor.
Owner:THE RES FOUND OF STATE UNIV OF NEW YORK

Dynamic tuning of chemiresistor sensitivity using mechanical strain

The sensitivity of a chemiresistor sensor can be dynamically tuned using mechanical strain. The increase in sensitivity is a smooth, continuous function of the applied strain, and the effect can be reversible. Sensitivity tuning enables the response curve of the sensor to be dynamically optimized for sensing analytes, such as volatile organic compounds, over a wide concentration range.
Owner:NAT TECH & ENG SOLUTIONS OF SANDIA LLC

Mercury sensor for detecting, differentiating, and measuring organic and inorganic mercury compounds

The invention relates to a sensor assembly to detect and quantify organic and / or inorganic mercury compounds, including elemental mercury that may be present in gases or liquids, such as natural gas, air, condensates, crude oil, refined petroleum gas or liquids, and water including connate water, condensed water and water containing hydrate inhibitor(s). The sensor assembly includes a housing having a flow channel defined by an inlet, a sensor array, and an outlet. The sensor array is based on the differential sorption properties measured using a surface acoustic wave (SAW) sensor array, a chemiresistor array, or a combination of the two.
Owner:CHEVROU USA INC

Wireless sensor system and methods

Incontinence management systems, methods, and sensors are provided that alert the caregiver when a patient's brief has been soiled. A resonant circuit includes a polyaniline / carbon black (PANI / CB) composite chemiresistor which undergoes a large impedance change upon exposure to the vapor or 'smell' of urine or feces. Due to the impedance change of the PANI / CB resistor, characteristics of the resonant circuit change when the sensor is exposed to urine or feces vapor. The sensor responds to an interrogating signal with a signal based least in part on the sensor's impedance and indicates the condition of the brief as soiled or clean.
Owner:JPTECH

Robust Low Resistance Vapor Sensor Materials

Compositions for sensor films used for detecting chemical analytes within sensors, such as polymer-absorption chemiresistors (i.e., conductometric sensors) are provided. Robust sensor film compositions that have low resistance, high conductivity, and greater temperature stability and sensitivity to chemical analytes are provided, as well as methods of making these sensor films. Such sensor film compositions include a matrix having a polymer resin and a plurality of conductive particles comprising an axial-geometry conductive particle. Exemplary axial-geometry conductive particles comprise graphene, such as a carbon nanotube. Blends of conductive particles are also contemplated, including blends of axial-geometry conductive particles, such as carbon nanotubes, and carbon black.
Owner:THERM O DISC

Temperature compensated vapor sensor

A chemiresistor sensor system that compensates for changes in resistance caused by changes in ambient temperature, thereby increasing the accuracy of the sensor system's ability to detect target analytes. The sensor system generally includes a first resistor, a second resistor, and a load regulator or switch that is sensitive to changes in ambient temperature. At least one of the first resistor and the second resistor is a sensing element having a resistance that changes in response to the presence of one or more of the analytes. The switch manages an electrical load across the first resistor and the second resistor. The switch prevents passage of the electrical load across the first and / or second resistor when the ambient temperature is at a first value. The switch permits passage of the electrical load across the first and / or second resistor when the ambient temperature is at a second value.
Owner:THERM O DISC

Temperature compensated vapor sensor

A chemiresistor sensor system that compensates for changes in resistance caused by changes in ambient temperature, thereby increasing the accuracy of the sensor system's ability to detect target analytes. The sensor system generally includes a first resistor, a second resistor, and a load regulator or switch that is sensitive to changes in ambient temperature. At least one of the first resistor and the second resistor is a sensing element having a resistance that changes in response to the presence of one or more of the analytes. The switch manages an electrical load across the first resistor and the second resistor. The switch prevents passage of the electrical load across the first and / or second resistor when the ambient temperature is at a first value. The switch permits passage of the electrical load across the first and / or second resistor when the ambient temperature is at a second value.
Owner:THERM O DISC

Vapor sensor and materials therefor

The present disclosure relates to a composition for sensor films used for detecting chemical analytes within sensors, such as polymer-absorption chemiresistors (i.e., conductometric sensors). The present disclosure provides robust sensor film compositions that have low resistance, high conductivity, and greater temperature stability and sensitivity to chemical analytes, as well as methods of making these sensor films. Sensor film compositions according to the present disclosure include a matrix having a polymer resin comprising siloxane and a plurality of conductive particles including at least two distinct species.
Owner:THERM O DISC

Multi-electrode chemiresistor

The invention relates to “solid state” chemiresistor sensors with electric control of the affinity of a chemosensitive material. The configurations of the present invention enable the fast regeneration of the sensor after analyte binding, which therefore increases selectivity. In one embodiment the chemiresistor sensor is implemented as a multi-electrode chemiresistor, comprising 4 electrodes for the separate measurement of the resistance of the chemosensitive material and the contact resistance, and 2 further electrodes to control the redox state of the chemosensitive sensor material, thereby facilitating fast and effective regeneration of the sensor.
Owner:BRANDENBURGISCHE TECHN UNIV COTTBUS SENFTENBERG

Chemiresistor for use in conducting electrolyte solution

The present invention provides a chemiresistor-based sensor for measuring the presence or amount of analyte in an electrolyte solution; said chemiresistor comprising (i) a chemiresistor film wherein the impedance of said nanoparticle film changes in the presence of an analyte; and (ii) two electrically conducting electrodes in electrical contact with said nanoparticle film; wherein said electrically conducting electrodes are adapted to be connected to a device for measuring the impedance of said chemiresistor film under a voltage signal and wherein the impedance of the double layer capacitor formed by the two electrically conducting electrodes in the presence of the electrolyte solution, is larger than the impedance of the chemiresistor film either before or after exposure of the chemiresistor film to the analyte. A method of using said chemiresistor-based sensor to measure the presence or amount of analyte is also provided. Further provided is a method of determining the partition coefficient of an analyte using said chemiresistor-based sensor.
Owner:COMMONWEALTH SCI & IND RES ORG
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