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52 results about "Benzoquinone Compound" patented technology

Positive electrode active material for nonaqueous secondary battery

The present invention provides a positive electrode active material for nonaqueous solvent secondary batteries, comprising, as an active ingredient, a 1,4-benzoquinone compound having lower alkoxy groups as substitutes, and a nonaqueous secondary battery comprising the positive electrode active material as a constituent. According to the invention, a nonaqueous secondary battery having a high energy density and excellent cycle characteristics can be obtained by using a positive electrode active material composed of an organic compound with a low environmental load.
Owner:NAT INST OF ADVANCED IND SCI & TECH

Method for synthesizing benzoquinone compound through catalytic oxidation of phenol compound

The present invention discloses a method for synthesizing a benzoquinone compound through catalytic oxidation of a phenol compound, and belongs to the technical field of synthesis of benzoquinone compounds. The method comprises: adding a reactant phenol compound, a solvent, a solid catalyst (onion carbon and the like) and an oxidant t-butyl hydroperoxide into a reactor, carrying out ultrasonic treatment to form a suspension, heating the suspension to a temperature of 70-100 DEG C, carrying out a reaction for 2-16 h, separating the reaction mixture to obtain a solid catalyst and a liquid mixture containing the benzoquinone compound, and carrying out separation purification on the liquid mixture to obtain the product benzoquinone compound. According to the present invention, the operation process is simple, and the used non-metal catalyst has characteristics of no corrosion, low price, green environmental protection and recycling; and the methyl phenol conversion rate is high, and the selectivity of the target product methyl-p-benzoquinone is good.
Owner:INST OF METAL RESEARCH - CHINESE ACAD OF SCI

Method for separating m,p-cresol mixture by adopting selective oxidation catalyst

The invention provides a method for separating an m,p-cresol mixture by adopting a selective oxidation catalyst. According to the method, the m,p-cresol mixture can be oxidized by using the selectiveoxidation catalyst, m-cresol in the mixture is completely oxidized into a benzoquinone compound, and p-cresol does not react. After the oxidation reaction is carried out, the boiling point differencebetween the benzoquinone compound (186-187 DEG C) and the p-cresol is significant, therefore, the complete separation of the p-cresol can be achieved through rectification. According to the separationmethod, during the oxidation reaction, oxygen or air is used as an oxidizing agent, the reaction conditions are very mild, the reaction operation is simple, the production cost is low, and the industrial production is easy. In addition, the generated benzoquinone compound through the reaction is an important dye and a raw material of an antioxidant, the high added value utilization can be achieved, and the economic benefit is good.
Owner:QINGDAO INST OF BIOENERGY & BIOPROCESS TECH CHINESE ACADEMY OF SCI

Method for producing polyphenylene ether

Method for producing polyphenylene ether, comprising preparing a polymerization solution of 10-25 parts by mass of a phenolic compound (M) and 75-90 parts by mass of an aromatic solvent (A) with the total of the compound and the solvent being 100 parts by mass, and 0.1-10 parts by mass of a catalyst (C) containing a metal salt; performing oxidative polymerization of the phenolic compound (M) by passing oxygen-containing gas through polymerization solution; stopping polymerization by mixing aqueous chelating agent solution into polymerization solution; subjecting a diphenoquinone compound produced as a by-product to quinone binding process or removal by reduction; and obtaining polyphenylene ether by separating aqueous phase through liquid-liquid separation. In the method for producing a polyphenylene ether, 0.001-0.004 part by weight of an ion catalyst (D) is added into the polymerization solution before the liquid-liquid separation.
Owner:ASAHI KASEI KK

Colored flame retardant charring agent tetraPEPA oxy-p-benzoquinone compound and preparation method thereof

The invention relates to a colored flame retardant charring agent tetraPEPA oxy-p-benzoquinone compound and a preparation method thereof. The structure of the compound is shown as the following formula in the specification. The preparation method includes: in a reactor equipped with a stirrer, a thermometer and a high-efficiency reflux condensation tube, adding a proper amount of an organic solvent and tetrachloro-p-benzoquinone, then adding a PEPA sodium salt that is 4-5 times the mole of tetrachloro-p-benzoquinone, performing heating to 100-160DEG C, carrying out heat preservation reaction for 6-9h, performing pumping filtration, removing sodium chloride, cooling and crystallizing the filtrate, and conducting filtering and drying, thus obtaining the reddish brown colored flame retardantcharring agent tetraPEPA oxy-p-benzoquinone. The compound provided by the invention has excellent flame retardant and charring properties, also has coloring effect, and is suitable for use as a flameretardant charring agent and coloring agent for nylon, polyester, polyurethane, rubber, polyolefin, unsaturated resin and other materials. Also the preparation method has the characteristics of one-step reaction, simple process and low equipment investment, and is easy to realize industrial production.
Owner:SUZHOU UNIV OF SCI & TECH

Magnetic silicon-lithium catalyst as well as preparation method and application thereof

The invention discloses a magnetic silicon-lithium catalyst as well as a preparation method and application thereof, and belongs to the field of chemical materials. The preparation method comprises the following steps: designing and synthesizing a magnetic Fe3O4@ SiO2 composite carrier, mixing lithium chloride, Fe3O4@ SiO2 and methanol, carrying out reflux reaction at 50-130 DEG C for 2-72 hours,performing cooling, carrying out rotary evaporation to remove excessive methanol after the reaction is finished, carrying out suction filtration, washing, and drying to obtain the silicon-lithium catalyst. The prepared magnetic silicon-lithium catalyst can be used in the synthesis of benzoquinone compounds, the chemical selectivity of the product is very high and can reach 100%, and the yield is over 90%; the catalyst can be recycled by an external magnet, the loss of active components is less, and the cost is saved. In addition, the catalyst provided by the invention can also be used for catalyzing bisphenol F synthesis, and has high reaction activity and selectivity.
Owner:JIANGNAN UNIV
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