247 results about "Lyotropic liquid crystal" patented technology

A personal cleansing composition comprising:

• a. from about 5% to about 50% by weight of an anionic detersive surfactant;
• b. from about 0.025% to about 5% by weight of a first cationic polymer having a cationic charge density of less than about 4 meq/gm, wherein said first cationic polymer forms an isotropic coacervate;
• c. from about 0.025% to about 5% by weight of a second cationic polymer having a cationic charge density of greater than or equal to about 4 meq/gm, wherein said second cationic polymer forms a lyotropic liquid crystal coacervate; and
• d. from about 20% to about 94% by weight of water.

A composition includes at least one organic compound of a first type of the general formula I and at least one organic compound of a second type of the general structural formula II, wherein Core in formula I is a conjugated organic unit capable of forming a rigid rod-like macromolecule, Gk is a set of ionogenic side-groups providing solubility of the organic compound of the first type in a solvent and give rigidity to the rod-like macromolecule; and wherein Sys in formula II is an at least partially conjugated substantially planar polycyclic molecular system capable of forming board-like supramolecules via π-π-interaction, and X, Y, Z and Q are substituents. The composition is capable of forming a lyotropic liquid crystal solution, which can form a solid retardation layer of biaxial type substantially transparent to electromagnetic radiation in the visible spectral range. The type and degree of biaxiality of the said optical retardation layer is controlled by a molar ratio of the organic compounds of the first and the second type in the composition. An optical film comprising a solid retardation layer formed of the composition, a method of producing the optical film, and a vertical alignment liquid crystal display using said retardation layer are also provided.

This invention provides composite materials that combine the material properties of hydrophobic polymers with internal structure and order provided by polymerization of lyotropic liquid crystals (LLCs). Composites, particularly nanocomposites, are made by forming a LLC assembly that has hydrophobic regions and hydrophilic regions, combining hydrophobic polymer in the assembly and polymerizing the polymerizable LLC monomers in the assembly. The hydrophobic polymer, polymerized LLC assembly or both can be crosslinked in the composite. Nanoporous composites, particularly those with uniform-sized pores and/or with uniform pores distribution can be prepared in this way. In addition, complex polymers in which a second polymeric material, which may be organic or inorganic, can be introduced into the pores or other structural features of the composite can be prepared. Adding flexible hydrophobic polymers to the LLC assembly increases the flexibility and toughness of the resultant polymerized composite material to provide improved composite materials for use as membranes and in other applications. Hydrophobic polymer addition can also increase the diffusion resistance in the organic phase of the composite. Of particular interest are composites in which the hydrophobic polymer is butyl rubber or related synthetic rubber.

The present invention relates to the fields of chemistry and biology and more particularly to the field of biomaterials. The present invention includes amphiphilic fibers and membranes, which can be used for biomembranes and biocompatible devices. The present invention also relates to processes for preparing amphiphilic fibers and membranes from solutions comprising amphiphilic molecules. More particularly, the present invention relates to processes for preparing fibers and membranes from electrospinning solutions comprising amphiphilic molecules. The present invention further provides fibers and nonwoven membranes comprising amphiphilic fibers chosen from anionic surfactants, cationic surfactants, nonionic surfactants, phospholipids, sulfobetaines, lyotropic liquid crystalline molecules, and/or block copolymers. Electrospun fibers offer the potential for direct fabrication of biologically based, high-surface-area membranes without the use of multiple synthetic steps, complicated electrospinning designs, or post-processing surface treatments. Polymeric phospholipids, for example, have been shown to be attractive candidates for blood purification membranes, artificial heart valves and organs, and other prosthetics, including other biocompatible devices.

The invention relates the organagel and liquid crystal-gel and preparing method. The structural formula of liquid crystal-gel is (R-O(CH2)nO-C6H4-NHCONH-)3(-1, 3, 5-C6H3) (R: 4-CN-C6H4N=NC6H4-, n>=4), and the structural formula of gel is (CH3(CH2)n-NHCO-)3(-1, 3, 5-C6H3) (n>=8). The mixture can make dioxide hexacyclic ring form organagel. The method comprises the following steps: heating the mixture, at the course of cooling, forming lyotropic liquid crystal, and then forming ordered arrangement liquid crystal-gel. The organagel and liquid crystal-gel can be used in catalysis, molecule switch, chemical sensing, drug delivery, drug segregation, specific optical device, and display unit and nanometer material mould.

An organic compound has the general structural formula I. In the formula I, Core is a conjugated organic unit capable of forming a rod-like macromolecule, n is a number of the conjugated organic units in the rod-like macromolecule, G_k is a set of ionogenic side-groups, and k is a number of the side-groups in the set G_k. The set of the ionogenic side-groups provide solubility of the organic compound or its salts and give rigidity to the rod-like macromolecule. The number n provides molecule anisotropy that promotes self-assembling of macromolecules in a solution of the organic compound or its salts, forming lyotropic liquid crystal. The solution is capable of forming a solid optical retardation layer of positive A-type substantially transparent to electromagnetic radiation in the visible spectral range. An optical film based on an organic compound of the general formula I and a method of making same are also disclosed.

Sulfoderivatives of perylenetetracarboxylic acid dibenzimidazole are provided. These compounds form liquid crystal systems possessing high quality optical properties. The resulting liquid crystal systems are readily applicable onto a substrate to obtain optically isotropic or anisotropic, at least partially crystalline films applicable in various fields.

A lyotropic liquid crystal composition comprises silver halide grains, silver grains or optically anisotropic grains dispersed in lyotropic liquid crystal. The grains have an aspect ratio of not less than 2.

The preparation process of ordered mesoporous monolithic silica includes the following steps: 1) selecting material including non-ionic surfactant, hydrochloric acid of pH value 0.5-2 and methyl metasilicate in the mass ratio of 0.5-2 to 1 to 1-4; 2) mixing the materials through stirring; 3) vacuum pumping for 5-20 min to obtain sol; 4) setting the sol in hydrothermal reactor to obtain gel, processing the gel with deionized water or solution of acid, alkali or salt at 60-120 deg.c for 12-72 hr, and extracting with ethanol or isopropanol to eliminate surfactant; and 5) heating at 40-110 deg.c for 10-48 hr to obtain optically transparent ordered mesoporous monolithic silica. The present invention has the features of short production period, simple process, high repeatability, etc. and the prepared mesoporous monolithic silica may be used as optical functional material, and other fields.

The invention provides cross-linked lyotropic liquid crystal (LLC) copolymers having ordered nanometer-sized pores lined with functional groups. The copolymers are formed by copolymerizing LLC monomers with strong LLC character and functionalized monomers with no or weak LLC character to form an LLC phase. Both the LLC monomers and the functionalized monomers contain hydrogen-bonding groups and hydrogen-bonding is believed to assist in the formation of the LLC phase of the blended mixture. Different classes of functional groups useful for the invention include, but are not limited to, acidic groups, basic groups, catalytic groups, oxidizing agents, reducing agents, polymerization initiators, binding agents, optically active groups, and electrically active groups. The invention also provides methods for making the cross-linked LLC copolymers of the invention. In these methods, the LLC monomer and the functionalized monomer are blended in a polar solvent, thereby allowing self-assembly of the first and second monomer into an LLC phase. The LLC phase in then cross-linked with retention of the LLC microstructure.