A kind of ozone catalytic oxidation catalyst and its preparation method and application
An ozone catalytic oxidation and catalyst technology, which is applied in catalyst activation/preparation, physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, etc., to increase added value, save tower equipment investment, and significantly economical effect of benefit
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Embodiment 1
[0050] The present embodiment is used to illustrate the preparation method of the ozone catalytic oxidation catalyst of the present invention and the ozone catalytic oxidation catalyst prepared by the method, and the present embodiment adopts the following method to prepare the catalyst:
[0051] (1) Grind the collected fly ash into fine powder, pass through an 80-mesh sieve, take 200 g of the fine powder and place it in a muffle furnace, roast at 600 ° C for 4 hours, wash and dry with water, and add a concentration of 5wt% nitric acid 6 g of the solution was extruded, and then calcined at 500 °C for 3 h to obtain a pretreated carrier;
[0052] (2), take 8.2 mL of cobalt nitrate aqueous solution containing 0.5 g / mL cobalt, 11.8 mL manganese nitrate aqueous solution containing 0.5 g / mL manganese, 13.6 mL copper nitrate aqueous solution containing 0.5 g / mL copper, and 0.5 g / mL iron containing 14.4mL of ferric nitrate aqueous solution and 212.3mL of calcium nitrate aqueous soluti...
Embodiment 2
[0054] The present embodiment is used to illustrate the preparation method of the ozone catalytic oxidation catalyst of the present invention and the ozone catalytic oxidation catalyst prepared by the method, and the present embodiment adopts the following method to prepare the catalyst:
[0055] (1) Grind the collected fly ash into fine powder, pass through a 200-mesh sieve, take 200 g of the fine powder and place it in a muffle furnace, roast it at 700 ° C for 5 hours, wash and dry it, and add a concentration of 5wt% nitric acid The solution was 8g, extruded, and then calcined at 550°C for 4h to obtain a pretreated carrier;
[0056] (2), using ultraviolet modified lamp radiation treatment above-mentioned pretreatment carrier, ultraviolet modified lamp power 250W, dominant wavelength 365nm, irradiation time 6h, obtain the carrier of ultraviolet radiation modification;
[0057] (3), take 10.4 mL of cobalt nitrate aqueous solution containing 0.5 g / mL cobalt, 10.2 mL manganese n...
Embodiment 3
[0059] The present embodiment is used to illustrate the preparation method of the ozone catalytic oxidation catalyst of the present invention and the ozone catalytic oxidation catalyst prepared by the method, and the present embodiment adopts the following method to prepare the catalyst:
[0060] (1) Grind the collected fly ash into fine powder, pass through a 200-mesh sieve, take 200 g of the fine powder and place it in a muffle furnace, roast it at 700 ° C for 5 hours, wash and dry it, and add a concentration of 5wt% nitric acid 10 g of the solution was extruded, and then calcined at 500 °C for 3 h to obtain a pretreated carrier;
[0061] (2), using ultraviolet modified lamp radiation treatment above-mentioned pretreatment carrier, ultraviolet modified lamp power 500W, dominant wavelength 365nm, irradiation time 12h, obtain the carrier of ultraviolet radiation modification;
[0062] (3), take 11.6 mL of cobalt nitrate aqueous solution containing 0.5 g / mL cobalt, 11.6 mL mang...
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