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Humidity-control composite film, and preparation method and application thereof

A composite film and polymer technology, applied in the field of moisture control composite film and its preparation, can solve the problems of high price, excessive chlorine content, and the composite film does not have intelligent moisture control, and achieves the effect of improving the moisture permeability.

Active Publication Date: 2021-08-20
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The temperature-sensitive and moisture-permeable membrane is prone to condensation on the surface of the membrane under high humidity and low temperature; the silicon filter membrane has a moisturizing function, but the moisture permeability cannot be changed with humidity; The performance meets the requirements, but the preparation process is not environmentally friendly, the process is complicated, and there may be problems with excessive chlorine content in the processing process
[0004] CN105986511A discloses the technology of applying natural polymers with good hydrophilic water retention and film-forming properties on base paper with high dry and wet strength, but the cost is relatively high
CN104029449A discloses a coating film with a large moisture permeability, the base layer is an expanded polytetrafluoroethylene film layer, and the coating is a polyurethane emulsion copolymer coating containing hemp stalk core ultrafine powder. Applicable to car lamp housings, but does not have intelligent humidity control performance
CN103507339A discloses a moisture-sensing and moisture-permeable film, which keeps regenerated cellulose in the base material of non-woven fabric, but does not have gas barrier properties
CN103107301A discloses a kind of inorganic coating lithium-ion battery diaphragm, comprises multi-layer structure, is respectively porous flexible base film and the coating that is coated on both sides of base film, coating comprises polyvinyl alcohol and zeolite particle, the auxiliary of this coating The composition does not contain metal salts, and the composite film does not have the function of intelligent moisture control
CN1864829A discloses a hydrophilic-hydrophobic bipolar composite membrane and its preparation method. The membrane has a double-layer structure, the bottom layer is a porous support layer, and the upper layer is a hydrophilic membrane containing lithium chloride. The membrane has high moisture permeability and It has a strong blocking effect on other gas molecules, but it does not have intelligent humidity control
WO2012133805A1 discloses a moisture-permeable membrane, the porous substrate is preferably polytetrafluoroethylene, which is expensive, and the high moisture-permeable performance of the membrane is not good
US20030054155A1 discloses a waterproof and moisture-permeable composite membrane, the hydrophobic layer is polytetrafluoroethylene, and the hydrophilic layer is polyurethane. The membrane has high moisture permeability, but does not have intelligent moisture control performance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0064] 2kg polypropylene is stretched into a polypropylene porous film on a film unidirectional stretching machine.

[0065] Add 5g of polyvinyl alcohol, 0.2g of nanometer zinc oxide, and 0.2g of glutaraldehyde into 94.6g of distilled water to fully dissolve. was added to the obtained solution, fully stirred until the mixture was uniform, and the pH of the solution was adjusted to 2 with sulfuric acid to obtain a coating solution. Brush this coating solution evenly on one side of the polypropylene porous film, then place it in an oven and dry it at 70°C for 10 minutes. Then the additional layer of polyvinyl alcohol of the composite film is contacted with 0.5% 2-acrylamido-2-methylpropanesulfonic acid and 0.05% aqueous solution of potassium persulfate for 1 min, and drained; the obtained film Put it into a microwave reactor with a modulating power of 120w. After 2 minutes of reaction, a moisture-controlling composite film A1 is obtained. The thickness of the base layer is 70 m...

Embodiment 2

[0067] 2kg polypropylene is stretched into a polypropylene porous film on a film unidirectional stretching machine.

[0068] Add 1g of gum arabic, 0.1g of nano-silver, and 0.1g of glutaraldehyde into 98.8g of distilled water to fully dissolve. was added to the obtained solution, fully stirred until the mixture was uniform, and the pH of the solution was adjusted to 2 with sulfuric acid to obtain a coating solution. Brush this coating solution evenly on one side of the polypropylene porous film, then place it in an oven and dry it at 90°C for 5 minutes. Then the additional layer of gum arabic of the composite membrane was contacted with 2-acrylamido-2-methylpropanesulfonic acid and 0.5% sodium persulfate aqueous solution containing 5% mass concentration for 1min, and drained; the obtained membrane was placed in In a microwave reactor, after adjusting 300w and reacting for 30s, the moisture-controlling composite film A2 was obtained. More than 85% of the pores; the thickness o...

Embodiment 3

[0070] 2kg of polyethylene is stretched into a polyethylene porous film on a film unidirectional stretching machine.

[0071] Add 8g of hydroxypropyl methylcellulose, 0.5g of nano-silver, and 0.5g of glutaraldehyde into 91g of distilled water to fully dissolve. was added to the obtained solution, fully stirred until the mixture was uniform, and the pH of the solution was adjusted to 2 with sulfuric acid to obtain a coating solution. Brush this coating solution evenly on one side of the polypropylene porous film, then place it in an oven and dry it at 90°C for 5 minutes. Then, after contacting the additional layer of hydroxypropyl methylcellulose of the composite membrane with 2-acrylamido-2-methylpropanesulfonic acid with a mass concentration of 2% and 0.2% ammonium persulfate aqueous solution for 1 min, drain the liquid; The obtained membrane was placed in a microwave reactor, adjusted to 200w for 5 minutes, and the humidity control composite film A3 was obtained. The thickn...

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Abstract

The invention relates to a humidity-control composite film, and a preparation method and application thereof. The humidity-control composite film comprises a base layer and an additional layer, and the additional layer is located on one side of the base layer. The base layer is a porous film, and the additional layer comprises a multi-element hydroxyl polymer and an optional antibacterial agent; and the surface of the additional layer is a surface modification layer grafted with 2-acrylamido-2-methylpropanesulfonic acid, and the surface modification layer is grafted to the surface of the additional layer through a microwave branching reaction. The humidity-control composite film has the intelligent humidity control capability, keeps the humidity of fruits and vegetables when the relative humidity is relatively low, increases the moisture permeability when the relative humidity is relatively high so as to prevent the fruits and vegetables from dew formation and ulceration, has the oxygen barrier property, and can be used for a fruit and vegetable box with a fresh-keeping function and a refrigerator with the fresh-keeping fruit and vegetable box.

Description

technical field [0001] The invention relates to the field of functional films, in particular to a humidity control composite film and its preparation method and application. Background technique [0002] Fruits and vegetables are important foods for human beings, and they are the main sources of basic nutrients (vitamins, minerals, complex carbohydrates, etc.). With the improvement of people's living standards, the requirements for the freshness of fresh fruits and vegetables are getting higher and higher. Fruits and vegetables can continue to carry out life activities such as respiration and transpiration after harvesting, and water loss and nutrient consumption will occur during storage. For every 10°C increase in temperature, the respiratory intensity of fruits and vegetables doubles. The way to keep fruits and vegetables fresh at home is to store fruits and vegetables in the refrigerator to slow down the respiration of fruits and vegetables. In fruits and vegetables, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J9/36C08J5/18C08L23/12C08L23/06C09D129/04C09D105/00C09D101/28C09D105/08C09D105/04C09D7/61C09D7/63A23B7/159B65D85/34B65D65/02
CPCC08J9/36C08J9/365C08J5/18C09D129/04C09D105/00C09D105/08C09D105/04C09D101/284C09D7/61C09D7/63A23B7/159B65D85/34B65D65/02C08J2323/12C08J2323/06C08K2201/011C08K2003/2296C08K2003/0806C08K3/22C08K5/07C08K3/08B23B27/08C08J7/054C08J7/0427C08J2429/04C08J2401/28C08J2407/00C08J2405/08C08J2405/04
Inventor 张杨宋建会郑萃唐毓婧姚雪容潘国元刘轶群
Owner CHINA PETROLEUM & CHEM CORP
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