Preparation method of flame-retardant polyurethane aluminum alloy composite board
A technology of polyurethane and composite boards, which is applied in the field of polymer materials, can solve the problems of blocking the full bonding of the board layers, uneven bonding and dispersion of adhesives, and poor bonding, so as to improve compatibility and mechanical properties, Save the film lamination process and improve the effect of curing performance
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Embodiment 1
[0019] (1) In parts by weight, at a temperature of 25°C and a relative humidity of 50%, add 53 parts of norbornane diisocyanate into a three-necked bottle in a reaction kettle, add dropwise and evenly disperse Catalyst 0.03 parts of bismuth isooctanoate and 83 parts of polyacrylate polyol, control the temperature at 50°C, react for 1h, then raise the temperature to 75°C, add 20 parts of tetrabromophthalic acid diol dropwise at a constant speed for 40min, and continue the reaction 1h, stop heating, and when the temperature in the reactor drops to 40°C, slowly add 25 parts of plasticizer tris(2-chloropropyl) phosphate, 0.8 parts of coupling agent sodium zirconium lactate, and 0.9 parts of water reducer triterpene Saponin, 21 parts of NCO-terminated polyurethane prepolymer, vacuumize to below -0.08Mpa and stir until the material is uniform, nitrogen protection to release pressure, add 42 parts of inorganic filler zinc borate, vacuum to below -0.09Mpa and stir at 35°C Until the ma...
Embodiment 2
[0023] (1) In parts by weight, at a temperature of 25°C and a relative humidity of 50%, add 453 parts of norbornane diisocyanate into a three-necked bottle in a reaction kettle, add dropwise and evenly disperse The catalyst is 0.01~0.03 parts of bismuth isooctanoate and 75 parts of polyacrylate polyol, the temperature is controlled at 25°C, the reaction is 0.5h, and then the temperature is raised to 70°C, and 15 parts of tetrabromophthalic acid diol is added dropwise at a constant speed for 35 minutes. , continue to react for 1 hour, stop heating, and when the temperature in the reactor drops to 40°C, slowly add 22 parts of plasticizer resorcinol bis(diphenyl phosphate), 0.5 parts of coupling agent 2-methacrylic acid Chromium chloride, 0.7 parts of water reducer sodium polystyrene sulfonate, 15 parts of NCO-terminated polyurethane prepolymer, vacuumize to below -0.08Mpa and stir until the material is uniform, nitrogen protection and pressure release, add 35 parts of inorganic f...
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