Magnetic fibre and manufacture method thereof

A magnetic fiber and manufacturing method technology, applied in fiber processing, rayon manufacturing, fiber chemical characteristics, etc., can solve problems such as functional decline, functional interference, and non-obvious fiber magnetic properties

Active Publication Date: 2010-02-17
TIANJIN POLYTECHNIC UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the fiber can have both magnetic and far-infrared functions, it also has the following disadvantages: on the one hand, due to the low content of magnetic powder, the magnetic properties of the fiber are not obvious; on the other hand, the far-infrared particles achieve For the health care effect on the human body, the magnetic powder particles play a health care effect on the human body through a magnetic field of a certain strength. Because the health care mechanism of the two is different, the magnetic powder and far infrared are mixed and used to make magnetic far infrared health care fibers, which will make them The functions of each other interfere with each other, resulting in a decline in function, especially affecting the performance of its magnetic properties.
However, within the scope of the applicant's search, there are no public reports on the magnetic fibers that have both magnetic functions and electromagnetic wave absorption and shielding functions (including microwave absorption and shielding functions).

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Take 89.7 parts of polyethylene terephthalate after drying (percentage by weight, the same below), 10 parts of ferric oxide with an average particle diameter of 0.2 μm, 0.1 part of polyethylene wax, triisostearyl titanic acid 0.2 parts of isopropyl ester, after being fully mixed, extruded through a twin-screw machine at 280°C, granulated to produce a fiber skin layer material; take 80 parts of polyethylene terephthalate, with an average particle size of 200nm 15 parts of iron powder, 5 parts of γ-glycidoxypropyltrimethoxysilane, after being fully mixed, extruded through a twin-screw machine at 270°C, granulated to produce a fiber core layer material; the obtained skin core After the material is fully dried, according to the volume ratio of fiber sheath and core of 7:3, the coiled yarn is spun with a skin-core composite spinning machine, and then the obtained coiled yarn is stretched 3 times at a temperature of 140 ° C to obtain a magnetic Fiber filaments are then magnet...

Embodiment 2

[0030]Take 57 parts of polypropylene with a melt index of 50, 40 parts of barium ferrite with an average particle size of 1.5 μm, and 3 parts of isopropyl tris(dodecylbenzenesulfonyl) titanate. Extrude by twin-screw at ℃ and granulate to produce fiber skin material; take 97.5 parts of polyethylene with a melt index of 30, 2 parts of nickel powder with an average particle size of 20nm, and γ-methacryloxytrimethoxysilane 0.5 parts, after being fully mixed, extruded by twin-screw at 190°C, granulated to produce a fiber core layer material; Spin the coiled yarn on the core composite spinning machine; stretch the obtained coiled yarn 4 times at a temperature of 95°C, cut it into short fibers of 50 cm, and then magnetize it at 11,000 Gauss for 0.05 minutes to obtain the finished magnetic fiber Short filament.

[0031] After testing, the average magnetic field strength of the fiber is 15 gauss, and the microwave reflection attenuation is 6db.

Embodiment 3

[0033] Take 68 parts of polyethylene with a melt index of 30, 25 parts of strontium ferrite powder with an average particle size of 1 μm, 5 parts of NdFeB magnetic powder, and 2 parts of isopropyl tris(dodecylbenzenesulfonyl) titanate , after thorough mixing, twin-screw extrusion and granulation at 180°C to produce fiber skin material; take 84 parts of polyethylene with a melt index of 30, 12 parts of cobalt powder with an average particle size of 150nm, N-β- (Aminoethyl)-γaminopropyltrimethoxysilane 4 parts, after thorough mixing, twin-screw extrusion at 170°C, granulation, to produce fiber core material; , core volume ratio for composite spinning, and then stretch the resulting wound yarn at 75°C for 3 times, and then magnetize it at 11,000 Gauss for 0.2 minutes to obtain finished short filaments of magnetic fibers.

[0034] After testing, the average magnetic field strength of the fiber is 12 gauss, and the microwave reflection attenuation is 11db.

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PUM

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Abstract

The invention discloses a magnetic fiber and a manufacture method thereof. The magnetic fiber has a sheath core structure in the volume ratio of a sheath to a core bing 3:7-7:3 and is characterized inthat the fiber sheath layer material comprises the following components in percentage by weight: 57-89.7 percent of sheath layer polymer, 10-40 percent of magnetic powder and 0.3-3 percent of bulkingagent; and the fiber core layer material comprises the following components in percentage by weight: 80-97.5 percent of core layer polymer, 2-15 percent of metal power and 0.5-5 percent of coupling agent. The manufacture method of the magnetic fiber adopts the magnetic fiber components in percentage by weight and comprises the following processes: 1. preparing the magnetic fiber sheath layer material; 2. preapring the magnetic fiber core layer material; 3. preparing a sheath core composite magnetic fiber and spinning the sheath layer material and the core layer material obtained in the step 1and the sep 2 according to the volume ratio of the fiber sheath to the fiber core being 3:7-7:3 into a long fiber thread or a short fiber thread; 4. carrying out fiber magnetization processing and magnetizing the long fiber thread or the short fiber thread obtained in the step 3 in the magnetic field strength of 11,000 gausses for 0.05-2 minutes.

Description

technical field [0001] The invention relates to functional chemical fiber technology, in particular to a magnetic fiber and a manufacturing method thereof. Background technique [0002] Magnetic fiber is a functional fiber with certain magnetic properties. There have been many patent literature reports on magnetic fibers at home and abroad. For example, Japanese Patent Hei 3-130413 introduces a method for manufacturing magnetic fibers by the skin-core method. The fiber skin layer is a polymer, and the core layer is a mixture of polymer and magnetic powder, and the content of the magnetic powder accounts for 5-70% of the fiber core material. Chinese patent document CN1252460 discloses a kind of magnetic health care fiber manufacturing technology. It is a magnetic health-care fiber made by fully mixing magnetic particles with far-infrared particles and carrier resin in proportion to make masterbatch, and then mixing with raw resin in proportion and spinning. The fibrous har...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F8/00D01F1/10D01D5/34D06M10/00D01F8/14D01F8/06D01F8/12
Inventor 齐鲁叶建忠邹建柱
Owner TIANJIN POLYTECHNIC UNIV
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