The invention relates to the technical field of organic photoelectric materials, specifically to a 3,4-diazaspirofluorene derivative and a synthetic method thereof, and an electronic device containingthe 3,4-diazaspirofluorene derivative. The 3,4-diazaspirofluorene derivative is as represented by a general formula (1) which is described in the specification. In the general formula (1), L1 to L3 each independently represent one or more selected from a group consisting of a single bond, a carbonyl group, an aromatic hydrocarbon group having 6 to 18 carbon atoms, and an aromatic heterocyclic group having 5 to 18 carbon atoms. According to the 3,4-diazaspirofluorene derivative disclosed by the invention, a 3,4-diazaspirofluorenone rigid structure is introduced, so the obtained 3, 4-diazaspirofluorene derivative is excellent in film-forming property and thermal stability, and can be used for preparing an organic light-emitting device, an organic field effect transistor and an organic solarcell. Furthermore, the 3,4-diazaspirofluorene derivative can be used as a constituent material of a hole injection layer, a hole transport layer, a light emitting layer, an electron blocking layer, ahole blocking layer or an electron transport layer, and can reduce driving voltage, improve efficiency, brightness, prolong service life and the like.