3,4-diazaspirofluorene derivative and synthetic method thereof and electronic device containing 3,4-diazaspirofluorene derivative
A technology of fluorene derivatives and diazaspiro, which is applied in the field of organic optoelectronic materials to achieve good film-forming properties and thermal stability, good application effects, high electron injection and movement rates
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0156] Embodiment 1: the synthesis of compound 15
[0157] (Synthesis of Intermediate 1-1)
[0158] The synthetic route of intermediate 1-1 is as follows:
[0159]
[0160] Under the protection of nitrogen, 2-bromobiphenyl (2.0 g, 8.9 mmol) and 150 mL of anhydrous tetrahydrofuran were added into a dry and clean 250 mL three-necked flask, and stirred and dissolved at room temperature. The system was cooled to -78°C, and 3.9 mL (2.5 M, 9.8 mmol) of n-butyllithium was added dropwise at this temperature, and stirring was continued at this temperature for 1.5 h after the addition was completed. Then 3-(4-bromophenyl)-5H-indolo[1,2-c]pyridazin-5-one (2.7g, 8.1mmol) was added in one go, and the cooling bath was removed after the addition, and the reaction was spontaneous Warm to room temperature and continue stirring overnight. After the reaction, it was washed with water, dried, and spin-dried to obtain a white solid.
[0161] The above white solid was transferred to a 250 mL...
Embodiment 2
[0166] Embodiment 2: the synthesis of compound 99
[0167] (Synthesis of Intermediate 1-2)
[0168] The synthetic route of intermediate 1-2 is shown below:
[0169]
[0170] Under the protection of nitrogen, 2-bromotriphenylamine (2.9 g, 8.9 mmol) and 150 mL of anhydrous tetrahydrofuran were added into a dry and clean 250 mL three-necked flask, and stirred and dissolved at room temperature. The system was cooled to -78°C, and 3.9 mL (2.5 M, 9.8 mmol) of n-butyllithium was added dropwise at this temperature, and stirring was continued at this temperature for 1.5 h after the addition was complete. Then 3-(4-bromophenyl)-5H-indolo[1,2-c]pyridazin-5-one (2.7g, 8.1mmol) was added in one go, and the cooling bath was removed after the addition, and the reaction was spontaneous Warm to room temperature and continue stirring overnight. After the reaction, it was washed with water, dried, and spin-dried to obtain a white solid.
[0171] The above white solid was transferred to a ...
Embodiment 3
[0180] Embodiment 3: the synthesis of compound 337
[0181] (Synthesis of Intermediates 1-4)
[0182] The synthetic routes of intermediates 1-4 are shown below:
[0183]
[0184] Under the protection of nitrogen, 1-bromo-8-phenylnaphthalene (2.5 g, 8.9 mmol) and 150 mL of anhydrous tetrahydrofuran were added to a dry and clean 250 mL three-necked flask, and stirred to dissolve at room temperature. The system was cooled to -78°C, and 3.9 mL (2.5 M, 9.8 mmol) of n-butyllithium was added dropwise at this temperature, and stirring was continued at this temperature for 1.5 h after the addition was completed. Then 3-(4-bromophenyl)-5H-indolo[1,2-c]pyridazin-5-one (2.7g, 8.1mmol) was added in one go, and the cooling bath was removed after the addition, and the reaction was spontaneous Warm to room temperature and continue stirring overnight. After the reaction, it was washed with water, dried, and spin-dried to obtain a white solid.
[0185] The above white solid was transferr...
PUM
| Property | Measurement | Unit |
|---|---|---|
| thickness | aaaaa | aaaaa |
| thickness | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to view more - R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap