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Integrated energy supply product, preparation method thereof and device

A product and energy technology, which is applied in the field of energy supply products and its preparation, can solve the problems of small bendability, human injury, and heavy weight, and achieve the effects of improved stability and safety, safe and stable work, and low design difficulty

Inactive Publication Date: 2018-09-07
DONGTAI HI TECH EQUIP TECH (BEIJING) CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Traditional batteries have safety hazards
In the high temperature environment of traditional lithium batteries, the liquid electrolyte is easy to release chemical gas, which leads to the expansion of the battery and the growth of common lithium dendrites, etc., which are the causes of battery explosion.
When a traditional lithium battery is integrated with a solar cell, the temperature of the battery is likely to reach 40-50°C due to long-term exposure to the sun. The common liquid electrolyte is usually an organic solution of lithium salt, which is easy to release gas at high temperature. In the environment, bulges or even explosions will occur, causing harm to the human body
[0005] Traditional energy supply equipment also has the disadvantage of large volume and heavy weight, which is not conducive to the miniaturization and portability of electronic equipment
In addition, traditional energy supply equipment is generally not flexible. In the past, there were also thin-film lithium batteries prepared by spraying. The degree of bendability is small, and it is not flexible in the true sense. Easy to cause battery failure

Method used

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  • Integrated energy supply product, preparation method thereof and device
  • Integrated energy supply product, preparation method thereof and device

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0058] production material:

[0059] GaAs substrate, Ge substrate, aluminum-plastic film, flexible PET or PEN film, EVA glue, arsine (AsH 3 ), phosphine (PH 3 ), trimethylaluminum (TMAl), trimethylgallium (TMGa), trimethylindium (TMIn), silane (SiH4), H 2 S, diethyl zinc (DEZn), tetrachloromethane (CCl 4 ), etc.; metal foils such as stainless steel, copper, silver, etc.; targets such as LiCoO 2 , Li 3 PO 4 , Li 2 MnO 4 , Cu, Ag, Au, etc.; evaporation sources such as Li particles, Au particles, PEN organic evaporation sources, etc.

[0060] Preparation of triple-five double-junction batteries:

[0061] S1. GaAs substrate cleaning and drying. Use acetone or alcohol with ultrasonic cleaning, and then put it in the dryer to dry.

[0062] MOCVD (metal organic chemical vapor deposition) method is used to epitaxially grow sacrificial layer, buffer layer, emitter layer, tunnel junction, window layer, etc. on the GaAs substrate in sequence. The precursor gas introduced in the...

Embodiment 2

[0090] Preparation of triple-five double-junction batteries:

[0091] Step 1. Use Ge substrate to reduce cost. MOCVD (metal organic chemical vapor deposition) method is used to epitaxially grow sacrificial layer, buffer layer, emitter layer, tunnel junction, window layer, etc. on the substrate in sequence. The precursor gas introduced in the MOCVD process is arsine (AsH 3 ), phosphine (PH 3 ), trimethylaluminum (TMAl), trimethylgallium (TMGa), trimethylindium (TMIn) and other gases. Doping with tetrabromomethane (CBr 4 ) and H 2 S.

[0092] In the epitaxial layer structure, the thickness of the substrate is 160 μm, and the thickness of the sacrificial layer is 80 nm; n-type Al 0.3 In 0.7 The thickness of the P window layer is 50nm, and the doping concentration is 1×10 19 cm -3 ; n-type Ga 0.5 In 0.5 P emitter region, thickness 50nm, p-type Ga 0.5 In 0.5 P base region, thickness 50nm, p-type Ga 0.5 In 0.5 P tunnel junction, thickness 30nm, n-type Al 0.1 Ga 0.9 A...

Embodiment 3

[0098] The flexible thin-film III-V solar cell has a photoelectric conversion efficiency of up to 29%. Embodiment 3 Preparation of all-solid-state thin-film lithium battery

[0099] In this embodiment, in step 1, a layer of SiO with a thickness of 100 nm is plated on the copper foil. 2 film.

[0100] Step 3 The magnetron sputtering chamber selects LiMn 2 o 4, deposited with a thickness of 80nm to form the positive electrode of a lithium battery. After the deposition, the sample stage was heated to 400°C-500°C, and annealed for about 15 minutes to obtain a film with uniform grain size, and then cooled naturally.

[0101] In step 5, the thickness of the LiPON electrolyte film is 100nm.

[0102] Other operations are the same as in Example 1.

[0103] The present invention adopts the integrated integration of thin-film solar cells and thin-film lithium batteries to realize soft, bendable and easy-to-carry batteries, making electronic products lighter in weight. The third an...

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Abstract

The invention provides an integrated energy supply product. The product integrates a III-V thin film solar battery and an all-solid-state thin film lithium battery; the positive electrode of the solarbattery is connected with the positive electrode current collector of the lithium battery; the negative electrode of the solar battery is connected with the current collector of the negative electrode Li of the lithium battery; and the positive electrode current collector and negative electrode current collector of the lithium battery are connected with a load through wires. The invention also provides a preparation method of the energy supply product and a device for preparing the energy supply product. The device comprises a glove box; and a magnetron sputtering coating device, a vacuum evaporation device and a hot pressing device are integrated in the glove box. According to the energy supply product of the invention, the III-V thin film solar battery is adopted; the III-V thin film solar battery is provided with a light-weight flexible substrate; the overall thickness of the solar battery is smaller than 200 micrometers; the weight-to-area ratio of the solar battery is 300 g / m<2>and is much smaller than the weight-area ratio of a crystalline silicon battery; the all-solid-state thin film lithium battery is adopted, and is provided with a flexible substrate; the thickness of the entire energy supply product is smaller than 1 mm; and the energy supply product is flexible, light-weight and easy to carry.

Description

technical field [0001] The invention belongs to the field of energy technology, and in particular relates to an energy supply product integrated with a solar battery and a lithium battery, and a preparation method and equipment thereof. Background technique [0002] With the increasing thinness of electronic products, the power supply devices are increasingly required to be thin, safe, and efficient. At present, most of the batteries in electronic products such as mobile phones and computers have problems such as short battery life, large volume, and heavy weight, which restrict the development of electronic products. the bottleneck. In order to achieve a longer battery life, some inventions combine solar cells with lithium batteries, which can use the continuous energy of the sun's light source to achieve unlimited battery life, such as patents CN 105789723A and CN105789372A, which combine copper indium gallium selenide flexible solar cells The combination of batteries can...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L31/0392H01L31/0445H01L31/0304H01L31/18H02S40/38H01M10/0585H01M10/0562H01M10/46
CPCH01L31/03046H01L31/03926H01L31/1844H01L31/1852H01M10/0562H01M10/0585H01M10/465H01M2220/30H01L31/0445H02S40/38Y02E10/544Y02E60/10Y02E70/30Y02P70/50Y02A30/14
Inventor 胡晓侯珊珊梁慧刘琦
Owner DONGTAI HI TECH EQUIP TECH (BEIJING) CO LTD
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