Preparation method of electrode slice with high electrochemical performance

An electrochemical and electrode sheet technology, which is applied in the field of electrode sheet preparation, can solve the problems of low energy density of electrochemical capacitors, poor performance of porous carbon material products, and difficult control of pore structure, so as to achieve infiltration and rich pore structure. Sequence and pore structure rich and diverse effects

Inactive Publication Date: 2018-09-04
HENAN INST OF ENG
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, when using the existing technology to prepare porous carbon materials for electrochemical capacitors, non-renewable resources such as pitch, petroleum tar, and coal are mostly used as the main raw materials, and the preparation cost is high. Poor, the pore structure is not easy to control, and the specific surface area is still small (about 1000m 2 / g) and poor conductivity, the prepared electrochemical capacitor has low energy density, small specific capacity, poor electrochemical performance, and causes a certain degree of environmental pollution.

Method used

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  • Preparation method of electrode slice with high electrochemical performance
  • Preparation method of electrode slice with high electrochemical performance
  • Preparation method of electrode slice with high electrochemical performance

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Experimental program
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Effect test

Embodiment 1

[0035] Embodiment 1: the preparation method of banana peel-based activated carbon electrode sheet

[0036] (1) Wash the impurities on the surface of the banana peel, cut them into pieces with clean scissors, put them in a 101-2 oven produced by Shanghai Sanfa Instrument Co., Ltd., and dry them, and then pre-treat the banana peels: The dried banana peels are heated in a crucible and then placed in a muffle furnace, pre-oxidized at 250°C for 2-4 hours, and then cooled to room temperature to obtain pre-oxidized banana peels;

[0037] (2) Preparation of activated carbon: Preoxidized banana peel and ZnCl 2 Mix according to the mass ratio of 1:3, and add distilled water to make it fully mixed. After soaking for 24 hours, put the mixture in a blast drying oven to dry for 1.5 to 3 hours, and then put it in a tube resistance furnace. 2 In the presence of an inert atmosphere, the temperature was raised to 600, 700, 800, and 900°C at a rate of 5°C / min, and the temperature was gradually ...

Embodiment 2

[0042] Embodiment 2: performance test experiment

[0043] Each sample in embodiment 1 is carried out performance test from the following aspects, specifically as follows:

[0044] 1. Structural characterization

[0045] (1) XRD test

[0046] Select the D8 ADVANCE X-ray diffractometer produced by German Bruker Company to scan and carry out XRD test on the sample in Example 1, specifically: first grind the sample to be tested into powder, fill the sample tank and compact it, and set the working voltage of the instrument 35kV, scanning range 2θ=10~90°, the test results are as followsfigure 1 shown.

[0047] figure 1 The XRD curves of activated carbon obtained after activated carbonization at different temperatures are shown. It can be seen from the figure that the banana peel-based activated carbon has an obvious 002 peak at about 25°, and a low-intensity 100 peak near 42°, which shows that the obtained activated carbon is mainly amorphous. The activated carbon has a graphit...

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Abstract

The present invention discloses a preparation method of an electrode slice with a high electrochemical performance. The method comprises the steps of: performing preoxidation of banana skin in a condition of a temperature with 200-300 DEG C, cooling the banana skin to a room temperature to mix the banana skin with activating agent according to a 1:1-4 of a quantity relative ratio, adding water tothe mixed banana skin for immersion of the mixed banana skin for 24 hours, and performing drying; performing carbonization of the mixed banana skin in an inert atmosphere for 2-4h with a carbonizationtemperature of 600-900 DEG C, cooling the banana skin after carbonization to the room temperature and then performing acid pickling, performing water washing of the banana skin to be neutral, performing drying, and obtaining banana skin-based activated carbon; and performing mixing by a mass ratio of 21:2:2 of the activated carbon: conductive carbon black: polytetrafluoroethylene emulsion, and preparing a banana skin-based activated carbon electrode slice. The prepared electrode materials are a high specific surface area, the hole structures are various, the connection of the hole channels and carbon skeletons are tidy and ordered in size to facilitate infiltration of the electrolyte solution so as to facilitate transportation and diffusion of electrolyte ions and allow the electrode materials to have a good electrochemical performance and large specific capacitance.

Description

technical field [0001] The invention relates to the technical field of preparation of activated carbon electrode sheets, in particular to a method for preparing an electrode sheet with high electrochemical performance. Background technique [0002] Electrochemical capacitor is the principle that ions in the electrolyte solution generate an electric double layer between the solid conductive motor and the electrolyte solution interface through electrostatic attraction, or a capacitor made by the principle of storing charge through the surface Faraday redox reaction. It is a dielectric A new type of energy storage device between capacitors and batteries, it has extremely high safety, energy conversion efficiency and long cycle life, and is an ideal device to replace batteries. [0003] Due to the rich pore structure and high porosity of porous carbon materials, porous carbon materials represented by activated carbon have become the first choice for the preparation of electroche...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G11/86
CPCH01G11/86Y02E60/13
Inventor 李思雨石素宇陈垒刘鹏王非
Owner HENAN INST OF ENG
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