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Catalyst for high temperature catalytic decomposition of N2O and preparation method thereof

A high-temperature catalysis and catalyst technology, which is applied in the direction of physical/chemical process catalysts, separation methods, chemical instruments and methods, etc., can solve the problems of poor high temperature resistance stability and inability to meet high airspeed operation, etc., and achieve high lateral compressive strength and appearance Uniform, low and high temperature active effect

Active Publication Date: 2016-02-24
四川蜀泰化工科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the above studies can only meet some of the harsh conditions. For example, catalysts such as zirconium can meet high space velocity operation, but have poor high temperature stability. Catalysts such as magnesium and cobalt can achieve high temperature activity and stability, but cannot meet high space velocity operation.

Method used

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  • Catalyst for high temperature catalytic decomposition of N2O and preparation method thereof

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preparation example Construction

[0035] 1. Preparation of titanium, magnesium, zirconium, cerium solid solution carrier

[0036] (1) Preparation of carrier powder

[0037] Inject 1.0L of deionized water into the neutralization tank and heat to 40-90°C, weigh 230g of titanium nitrate, 182.3g of magnesium nitrate, 656.7g of cerium nitrate, 162.3g of zirconium nitrate and 496.5g of citric acid into the In the tank, keep stirring vigorously to maintain the temperature at 40-90°C, and adjust the pH. During the addition process, keep stirring vigorously, and continue to stir for 2 hours after the addition is completed to complete the reaction. After the reaction is complete, add 65.7g of pseudo-boehmite or aluminum hydroxide into the neutralization tank and stir evenly. Then stand still, if a small amount of clear liquid is formed on the upper part of the neutralization tank solution, the upper clear liquid is sucked out with a siphon, and the lower part of the sediment is released through the lower valve of the ...

Embodiment 1

[0044] Dissolve 300g of cobalt nitrate in 500mL of deionized water, stir to dissolve and place in a water bath at a constant temperature of 40-90°C. Put 200g of the prepared carrier in the solution for immersion for 30min, dry at 120°C for 60min after impregnation, and roast at 400°C for 10h after drying; impregnate, dry, dry, and calcinate again to obtain 1# finished catalyst.

Embodiment 2

[0046] Dissolve 300g of cobalt nitrate and 43.5g of praseodymium nitrate in 500mL of deionized water, stir to dissolve and place in a water bath at a constant temperature of 40-90°C. Put 200g of the prepared carrier in the solution for immersion for 30min, dry at 120°C for 60min after impregnation, and roast at 500°C for 10h after drying; impregnate again, dry, dry, and calcinate to obtain 2# finished catalyst.

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Abstract

The invention discloses a catalyst for performing high-temperature catalytic decomposition of N2O and a preparation method of the catalyst and belongs to the technical field of environment-friendly catalytic materials and atmospheric pollution treatment. The catalyst for performing high-temperature catalytic decomposition of N2O is prepared by taking a solid solution containing titanium, magnesium, zirconium and cerium as a carrier, taking transition metal oxides supported by the carrier as active components of the catalyst, and adding a suitable quantity of accessory ingredients, wherein the transition metal oxides account for 1-15% of the total mass of the catalyst; the accessory ingredients account for 1-5% of the total mass of the catalyst; the accessory ingredients are selected from one or several of scandium oxide, ferric oxide, sodium oxide, chromic oxide, yttrium oxide and rare earth oxide. Compared with the foreign mainstream products, the catalyst for performing high-temperature catalytic decomposition of N2O is uniform in appearance, high in edgewise compressive strength, large in specific surface area and low in shrinking ratio. The activity detection shows that the activity of the catalyst of our company is equivalent to the activities of the foreign mainstream products at the temperature of about 860 DEG C; the catalyst disclosed by the invention is excellent in activity at high and low temperatures, wide in temperature zones of activity and excellent in high-temperature activity stability.

Description

technical field [0001] The invention relates to the technical field of industrial catalysis, in particular to a catalyst for high-temperature catalytic decomposition of N 2 Catalysts for O and methods for their preparation. Background technique [0002] Due to the growth of world population, the rapid development of cities and the continuous increase of energy consumption per capita, the natural environment in which human beings live has been severely impacted, the environmental quality has declined, and the subsequent hazards to human health and the destruction of ecosystems It has become a common concern of people, and environmental protection and sustainable development have become one of the most urgent tasks for contemporary people. [0003] The major greenhouse gases currently in the atmosphere include CO 2 , CH 4 , N 2 O, HFCs, PFCs and SFs 6 . Among them, N 2 O not only produces the greenhouse effect, but also is a serious atmospheric pollutant. N 2 O is a t...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/83B01D53/86B01D53/56
CPCY02C20/10
Inventor 李华波许云波严会成李文静
Owner 四川蜀泰化工科技有限公司
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