The present invention relates to a piston ring (10), particularly a compression ring, for an internal combustion engine, comprising a ring-shaped body (11) having a ring joint formed by butt ends (14a, 14b), the ring-shaped body (11) further having a ring contact face (12) along its perimeter, for contacting a cylinder wall in operation. According to the invention, the ring contact face (12) has a barrel-shaped profile, the barrel-shaped profile having in any of its cross-sections an area of maximum curvature, whose radius of curvature increases in the direction of the butt ends (14a, 14b).