The invention relates to a herbicide prepared by binary complex formulation of pendimetalin and oxyfluorfen, and the herbicide is composed of the following ingredients by weight: 33% of the pendimethalin, 5% of the oxyfluorfen, 12% of a synergistic agent, 15% of an emulsifier and 35% of a solvent. The herbicide solves the problems that herbicides in the prior art are not wide in used crops and less in weed killing species, is a high efficient, high-speed contact-killing broad-spectrum herbicide, can control annual weeds, can completely achieve effective control of harm of weed communities in fields by one time of herbicide application, can realize no weed in the whole growth period of crops, is safe to the crops, and has no adverse effects on afterreap crops, the application amount of the herbicide in each mu of field is 24-36g, and the cost of application is reduced by 55 to 42% compared with single use of the pendimethalin and oxyfluorfen.