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Electroplating solution for surface of metal tool and electroplating process

A metal tool and electroplating solution technology, applied in electrolysis process, electrolysis components, cells, etc., can solve the problems of endangering the health of silver plating workers, failure to maintain silvery white color, and non-environmental protection of the coating, so as to reduce the harm to the human body No harm, environmental and human friendly, high plating efficiency effect

Pending Publication Date: 2021-10-01
深圳市加逸科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The main coatings used in the prior art include hexavalent chromium, copper-tin alloy, silver, gold, etc., but the sewage generated by the electroplating hexavalent chromium process is difficult to handle, which seriously pollutes the environment and the coating is not environmentally friendly; the copper-tin coating can only withstand 80~ 100°C, if the temperature exceeds this temperature, the coating will turn black and blue, and cannot maintain the silvery white color; the most commonly used silver plating solution in the silver plating process is the silver plating solution containing cyanide, because cyanide is a strong Toxic substances, this silver plating solution containing cyanide will greatly endanger the health of the silver plating process workers; although the gold plating process can improve the conductive contact resistance and enhance signal transmission, but its cost is high

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A kind of electroplating solution that is used for metal tool surface, it is composed of: chromium chloride 20g / L, zinc chloride 15 g / L, complexing agent 150 mL / L, buffering agent 16 mL / L and brightener 3 mL / L L, the balance is deionized water; The composition of described complexing agent, by mass fraction, comprises antimony potassium tartrate 3%, dithioethylene glycol 4%, ethylenediamine 20% and triethanolamine 10%, remaining The amount is deionized water; the composition of the brightener, by mass fraction, comprises polyethylene glycol 1%, sodium hydroxymethanesulfonate 10%, sodium vinylsulfonate 5% and benzylidene acetone 2%, and the remaining The volume is deionized water.

[0027] Wherein, the degree of polymerization of the polyethylene glycol is 1000-2000.

[0028] A kind of electroplating process that is used for metal tool surface, comprises steps as follows:

[0029] S1. Configure the electroplating solution, dissolve the soluble trivalent chromium salt a...

Embodiment 2

[0034] A kind of electroplating solution that is used for metal tool surface, it is composed of: chromium nitrate 35g / L, zinc nitrate 22 g / L, complexing agent 150 mL / L, buffering agent 26 mL / L and brightener 6 mL / L, Surplus is deionized water; The composition of described complexing agent, by mass fraction, comprises antimony potassium tartrate 8%, dithioethylene glycol 8%, dimethylethanolamine 15% and caprolactam 20%, surplus is Deionized water; the composition of the brightener, by mass fraction, comprises polyethylene glycol 2%, sodium naphthyl sulfonate 10%, allyl sodium sulfonate 10% and benzylidene acetone 2.5%, and the balance is Deionized water.

[0035] Wherein, the degree of polymerization of the polyethylene glycol is 1000-2000.

[0036] A kind of electroplating process that is used for metal tool surface, comprises steps as follows:

[0037] S1. Configure the electroplating solution, dissolve the soluble trivalent chromium salt and the soluble zinc salt of the fo...

Embodiment 3

[0042] A kind of electroplating solution that is used for metal tool surface, it is composed of: basic chromium sulfate 25g / L, zinc sulfate 15g / L, complexing agent 80mL / L, buffering agent 15mL / L and brightener 3mL / L L, balance is deionized water; The composition of described complexing agent, by mass fraction, comprises antimony potassium tartrate 1.2%, dithioethylene glycol 2%, dopamine 5%, isopropanolamine 5% and caprolactam 15%, and the balance is deionized water; the composition of the brightener, by mass fraction, comprises polyethylene glycol 2%, potassium naphthyl sulfonate 10%, potassium allyl sulfonate 5% and benzylidene acetone 2%, and the balance is deionized water.

[0043] Wherein, the degree of polymerization of the polyethylene glycol is 1000-2000.

[0044] A kind of electroplating process that is used for metal tool surface, comprises steps as follows:

[0045] S1. Configure the electroplating solution, dissolve the soluble trivalent chromium salt and the solub...

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PUM

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Abstract

The invention discloses an electroplating solution for the surface of a metal tool and an electroplating process, and belongs to the technical field of metal material processing. The electroplating solution is prepared from 18-35g / L of soluble trivalent chromium salt, 15-22g / L of soluble zinc salt, 80-150mL / L of complexing agent, 15-26mL / L of buffering agent, 3- mL / L of brightening agent and the balance deionized water; the complexing agent is prepared from, by mass, 1.2-10% of antimony potassium tartrate, 2-8% of dithioglycol, 25-35% of amine derivative and the balance deionized water; and the brightening agent is prepared from, by mass, 1-2% of polyethylene glycol, 15-20% of sulfonate, 2-3% of benzalacetone and the balance deionized water. The electroplating solution can effectively improve the surface performance of the metal tool, enhance the surface hardness and improve the wear resistance and corrosion resistance of the metal tool.

Description

technical field [0001] The invention belongs to the technical field of metal material processing, and in particular relates to an electroplating solution and an electroplating process for the surface of a metal tool. Background technique [0002] Electroplating is the process of plating a thin layer of other metals or alloys on the surface of certain metals using the principle of electrolysis. It is a process of using electrolysis to attach a layer of metal film to the surface of metal or other material parts to prevent metal oxidation ( Such as rust), improve wear resistance, electrical conductivity, reflectivity, corrosion resistance and enhance the appearance. [0003] The main coatings used in the prior art include hexavalent chromium, copper-tin alloy, silver, gold, etc., but the sewage generated by the electroplating hexavalent chromium process is difficult to handle, which seriously pollutes the environment and the coating is not environmentally friendly; the copper...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25D3/56C25D21/12C25D5/00
CPCC25D3/56C25D21/12C25D5/00
Inventor 韩红艳
Owner 深圳市加逸科技有限公司
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