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Rubber-plastic alloy material with excellent oil and corrosion resistance, and preparation method thereof

A rubber-plastic alloy and corrosion-resistant technology, applied in the field of rubber-plastic alloy materials, can solve the problems of rubber-plastic alloy performance constraints, influence on popularization and application, and easy to produce brittleness, etc., achieve excellent oil resistance and corrosion resistance, avoid agglomeration, and increase bonding force effect

Inactive Publication Date: 2020-04-21
安徽集讯科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Rubber-plastic alloy (NBR / PVC) is a kind of nitrile rubber (NBR) as the main base material, which is effectively modified by adding 30-50% mass fraction of polyvinyl chloride (PVC) and blended under specific process conditions. The resulting material rubber-plastic alloy has the dual characteristics of nitrile rubber and neoprene rubber. Through the closure of the double bond on the long chain of nitrile rubber by polyvinyl chloride macromolecules, the rubber-plastic alloy is endowed with excellent resistance to natural aging and ozone aging. At the same time, it not only retains the excellent oil resistance of nitrile rubber, but also has excellent solvent and chemical corrosion resistance and high mechanical properties, and has good dynamic flexibility. And self-extinguishing, nowadays, rubber-plastic alloy rubber has important commercial value and is widely used in the automobile industry and manufacturing industry. However, due to the poor thermal stability and impact resistance of polyvinyl chloride, whether it is hard or soft High-quality PVC is prone to brittleness during use, which will restrict the performance of the manufactured rubber-plastic alloy and affect its further promotion and application

Method used

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  • Rubber-plastic alloy material with excellent oil and corrosion resistance, and preparation method thereof

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Effect test

Embodiment 1

[0032] A rubber-plastic alloy material with excellent oil resistance and corrosion resistance, comprising the following components in parts by weight:

[0033] 45 parts of hydrogenated nitrile rubber, 30 parts of epoxy-solution polystyrene butadiene rubber, 10 parts of trans-1,4-polyisoprene, 85 parts of bisphenol A polycarbonate, vinyl-terminated methylbenzene 12 parts of base silicone oil, 8 parts of bis(2-ethylhexyl) phthalate, 10 parts of diaminopolyethylene glycol, 22 parts of polydopamine surface modified nano-silica, graphene / polyimide composite reinforcement 14 parts of fiber, 13 parts of sulfur, 1 part of vulcanization accelerator, 5 parts of stearic acid, 4 parts of microcrystalline paraffin, 1.2 parts of anti-aging agent, and 2 parts of flame retardant.

[0034] The preparation method of epoxidized solution-polymerized styrene-butadiene rubber is as follows:

[0035] Add solution-polymerized styrene-butadiene rubber into cyclopentane, the mass ratio of solution-pol...

Embodiment 2

[0043] A rubber-plastic alloy material with excellent oil resistance and corrosion resistance, comprising the following components in parts by weight:

[0044] 60 parts of hydrogenated nitrile rubber, 20 parts of epoxy-solution polystyrene butadiene rubber, 10 parts of trans-1,4-polyisoprene, 100 parts of bisphenol A polycarbonate, vinyl-terminated methylbenzene 15 parts of base silicone oil, 5 parts of bis(2-ethylhexyl) phthalate, 10 parts of diaminopolyethylene glycol, 22 parts of polydopamine surface modified nano-silica, graphene / polyimide composite reinforcement 15 parts of fiber, 20 parts of sulfur, 2 parts of vulcanization accelerator, 3 parts of stearic acid, 2 parts of microcrystalline paraffin, 1 part of anti-aging agent, and 1 part of flame retardant.

[0045] The preparation method of epoxidized solution-polymerized styrene-butadiene rubber is as follows:

[0046] Add solution-polymerized styrene-butadiene rubber into cyclopentane, the mass ratio of solution-polym...

Embodiment 3

[0054] A rubber-plastic alloy material with excellent oil resistance and corrosion resistance, comprising the following components in parts by weight:

[0055] 40 parts of hydrogenated nitrile rubber, 26 parts of epoxy-solution polystyrene butadiene rubber, 20 parts of trans-1,4-polyisoprene, 85 parts of bisphenol A polycarbonate, vinyl-terminated methylbenzene 10 parts of base silicone oil, 8 parts of bis(2-ethylhexyl) phthalate, 10 parts of diaminopolyethylene glycol, 25 parts of polydopamine surface modified nano-silica, graphene / polyimide composite reinforcement 16 parts of fiber, 10 parts of sulfur, 1 part of vulcanization accelerator, 4 parts of stearic acid, 2 parts of microcrystalline paraffin, 1 part of anti-aging agent, 2 parts of flame retardant.

[0056] The preparation method of epoxidized solution-polymerized styrene-butadiene rubber is as follows:

[0057] Add solution-polymerized styrene-butadiene rubber into cyclopentane, the mass ratio of solution-polymerize...

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PUM

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Abstract

The invention provides a rubber-plastic alloy material with excellent oil and corrosion resistance, and a preparation method thereof, and relates to the field of rubber-plastic alloy materials. The rubber-plastic alloy material comprises, by weight, 40-60 parts of hydrogenated butadiene-acrylonitrile rubber, 20-30 parts of epoxidized solution polymerized styrene-butadiene rubber, 10-20 parts of trans-1,4-polyisoprene rubber, 80-100 parts of bisphenol A polycarbonate, 10-20 parts of vinyl-terminated methyl phenyl silicone oil, 5-10 parts of di(2-ethylhexyl) phthalate, 8-15 parts of diamino polyethylene glycol, 22-28 parts of polydopamine surface modified nano-silica, 14-16 parts of graphene / polyimide composite reinforced fibers, 10-20 parts of sulfur, 1-2 parts of a vulcanization accelerator, 3-7 parts of stearic acid, 2-4 parts of microcrystalline wax, 1-2 parts of an anti-aging agent and 1-2 parts of a flame retardant. The rubber-plastic alloy material provided by the invention has excellent mechanical properties and excellent oil and corrosion resistance.

Description

technical field [0001] The invention relates to the field of rubber-plastic alloy materials, in particular to a rubber-plastic alloy material with excellent oil resistance and corrosion resistance and a preparation method thereof. Background technique [0002] Natural rubber has excellent properties such as resilience, insulation, water resistance and plasticity, and after proper treatment, it also has valuable properties such as oil resistance, acid resistance, alkali resistance, heat resistance, cold resistance, pressure resistance, wear resistance, etc. Therefore, it has Wide range of uses. Natural rubber has low tensile strength and hardness when used alone, and is limited in use. More than 70% of the rubber in the existing market is processed and used in the form of rubber or rubber and plastic. [0003] Rubber-plastic alloy (NBR / PVC) is a kind of nitrile rubber (NBR) as the main base material, which is effectively modified by adding 30-50% mass fraction of polyvinyl c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L69/00C08L15/00C08L9/00C08L83/07C08L71/02C08L79/08C08L91/06C08K13/06C08K9/04C08K3/36C08K3/04C08K3/06C08K5/12
CPCC08L69/00C08L2201/08C08L2205/035C08K2201/011C08L15/005C08L15/00C08L9/00C08L83/04C08L71/02C08L79/08C08L91/06C08K13/06C08K9/04C08K3/36C08K3/042C08K3/06C08K5/12D01D5/0038D01F6/74D01F1/10
Inventor 蔡娟
Owner 安徽集讯科技有限公司
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