Graphene oxide anti-abrasion ultra-high toughness concrete and preparation method and application thereof
An ultra-high toughness, graphene technology, applied in the direction of climate sustainability, sustainable waste treatment, solid waste management, etc., can solve the problem of poor impact toughness and abrasion resistance, high amount of ultrafine particles, limited applications, etc. problems, to achieve the effect of improving impact toughness and abrasion resistance, improving interfacial bond strength, and improving hydrophilicity
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[0048] The preparation method of shrinkage-reducing polycarboxylate superplasticizer:
[0049] 1) Add maleic anhydride into the reaction vessel, heat up to 55°C to melt it completely, then add diethylene glycol monobutyl ether and p-toluenesulfonic acid, heat up to 135°C, perform constant temperature esterification for 4.5 hours, and cool Purify by suction filtration afterward to obtain diethylene glycol monobutyl ether maleic anhydride monoester monomer with shrinkage function, wherein the mass ratio of maleic anhydride, diethylene glycol monobutyl ether and p-toluenesulfonic acid is 1:0.55:0.06 ;
[0050] 2) Add the diethylene glycol monobutyl ether maleic anhydride monoester monomer, methacrylic acid and sodium methacrylate sulfonate obtained in step 1) into a reaction vessel filled with distilled water, heat up to 95°C, and add dropwise Allyl polyethylene glycol and ammonium persulfate aqueous solution were reacted at a constant temperature of 95°C for 4 hours, and after ...
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[0062] A kind of graphene oxide anti-abrasion ultra-high toughness concrete, its preparation method comprises the steps:
[0063] 1) take each raw material by the proportioning in table 1;
[0064] 2) Add the machine-made sand, cement, silica fume and fly ash microbeads into the concrete mixer and stir for 3 minutes, then pour in the hydrophilic rubber particles and stir for 1 minute; put the graphene oxide dispersion and the shrinkage-reducing and viscosity-reducing water-reducing agent in the beaker Mix evenly in the medium, pour into the concrete mixer and stir for 2 minutes, then pour water into the concrete mixer and stir for 3 minutes, then add the composite expansion agent and stir for 1 minute to obtain the mixture; when the mixture becomes viscous, evenly add the mixed fiber and stir for 2 minutes. Finally, after mold loading, vibration, and molding, the surface is covered with an impermeable film for film curing, and then the mold is removed for standard curing or st...
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