A kind of preparation method of polymer composite film

A composite film and polymer technology, applied to biocide-containing paints, powder coatings, coatings, etc., can solve the problems of damaged coating adhesion, poor chemical resistance, poor weather resistance, etc., to achieve rich film types and functions, The dimensional stability of the product is good and the effect of widening the range of raw material selection

Active Publication Date: 2021-06-08
FOSHAN YIKEJU NEW MATERIAL CO LTD
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  • Description
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AI Technical Summary

Problems solved by technology

[0003] For multi-layer multifunctional composite films, the traditional preparation methods include: 1. Laminate the thermoplastic films that have been manufactured, and bond the layers with adhesives. 2. Adopt multi-layer co-extrusion molding, which is currently industrialized. The most 7-layer thermoplastic co-extrusion molding, thermoplastic multi-functional composite film has low surface hardness, poor thermal stability of size, large shrinkage rate, poor wear resistance, low strength, poor weather resistance, poor chemical resistance and other shortcomings
At the same time, the investment in these factories is huge, often hundreds of millions of RMB
[0004] On the other hand, paint strippable film-making technology is to coat high-temperature resistant materials such as glass, vitrified polished tiles, aluminum sheets, and iron sheets for multiple times, and it needs to peel off the cured paint film to form a film without damage. Industrial application is facing great challenges. At present, the main research and development direction in the coatings industry is to improve the adhesion of coatings on the substrate. Destroying the adhesion of coatings on the substrate and peeling off the substrate is an industry problem. Many use adhesion The peelable protective coating formed by poor water-based coatings also needs to be removed in heated alkaline water. In terms of solvent-based liquid coatings, most of them use acid-base or organic solvents to dissolve the paint film for peeling, and the paint film is damaged at the same time; In the powder coating industry, most of the paint film is removed by burning or soaking in strong solvents
[0005] The commonly used method of spraying release agent on plastic molds to achieve peeling is very small in practicality in this technical solution. Since the thickness of injection molded parts is several orders of magnitude thicker than that of film, the leveling of release agent has limited influence on the surface of injection molded parts. , but the current technology is limited, the leveling of solvent-free environmentally friendly coatings is difficult to achieve mirror effect without grinding and polishing, so it is necessary to use the flatness and smoothness of the substrate surface to achieve the specular highlight effect of the organic polymer composite film, if Spraying a release agent on a high-gloss substrate, the leveling and high-temperature volatilization of the release agent will seriously affect the high-gloss mirror effect of the film, and the release agent attached to the surface of the composite film will seriously affect the performance of the film. Therefore, for the application range The widest high-gloss composite film requires the use of environmentally friendly peeling technology that does not use mold release agents, organic solvents, or acids and bases

Method used

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  • A kind of preparation method of polymer composite film
  • A kind of preparation method of polymer composite film
  • A kind of preparation method of polymer composite film

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preparation example Construction

[0045] Traditional film production uses thermoplastics through blow molding, calendering, casting, multi-layer co-extrusion and other methods, but the present invention uses thermosetting coating materials and construction principles to make single-layer or multi-layer high-quality films with different functions. The molecular composite film is then peeled off from the substrate, with small equipment investment, flexible production organization, rich film types and functions, and personalized customization. The number of composite layers is not limited by the equipment, and the thickness can be adjusted flexibly; due to the wide variety of coatings, coating various functional coatings can realize more functions of the composite film. Specifically, such as figure 1 Shown, the preparation method of polymer composite film of the present invention comprises:

[0046] S101. Clean and dry the surface of the substrate.

[0047]The material of the substrate is glass, ceramic or meta...

Embodiment 1

[0098] 1) Selection of base material: choose a piece of ordinary white glass of 400*600*5mm, first wash the surface with clean water and dry it at 120°C for 5 minutes;

[0099] 2) One side of the cleaned and dried glass is protected against pollution, and this side is the back side;

[0100] 3) Paste the PET film on the front of the glass (let the use side face the glass), and fix it with carboxymethylcellulose sodium glue on the back of the glass;

[0101] 4) 96% of epoxy resin BE503 produced by Guodu Chemical Company and 2% of dicyandiamide curing agent produced by Ningxia Darong Company, and then add 0.5% leveling agent, 0.5% degassing agent, and 1% carbon black to make Powder coating, and then use electrostatic powder spraying equipment to spray the powder coating on the PET film that has completed step 3), and bake it in a hot air oven at a high temperature at 180 ° C for 15 minutes to form a layer of black film with a thickness of 30 μm. Coating, black coating and PET f...

Embodiment 2

[0106] 1) Selection of base material: choose a piece of ordinary white glass of 400*600*5mm, first wash the surface with clean water and dry it at 120°C for 5 minutes;

[0107] 2) One side of the cleaned and dried glass is protected against pollution, and this side is the back side;

[0108] 3) One side of the PET film is provided with a wood grain pattern, and the PET film is pasted on the front side of the glass (the wood grain pattern side is attached to the glass), and the back of the glass is fixed with sodium carboxymethyl cellulose glue;

[0109] 4) Use 95% epoxy resin NPES903 produced by Nanya Company and 2% dicyandiamide produced by Ningxia Darong Company as curing agent, add 1% leveling agent, 1% degassing agent, and 1% white pigment to make Powder coating, and then use electrostatic powder spraying equipment to spray the powder coating on the PET film that has completed step 3), and bake it in a hot air oven at a high temperature at 190°C for 15 minutes to form a wh...

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Abstract

The invention discloses a preparation method of a polymer composite film, comprising: (1) cleaning and drying the surface of a base material; (2) performing antifouling protection on one side of the cleaned and dried base material, the (3) wrap the thermoplastic film flatly on the front of the substrate; (4) spray the thermosetting powder coating on the thermoplastic film on the front of the substrate; (5) cure the substrate after spraying the thermosetting powder coating, Cool to normal temperature to form a composite film; (6) remove the antifouling protective material on the surface of the substrate and clean it; (7) place the substrate formed with the composite film to cool to normal temperature, peel the film off the surface of the substrate, And carry out winding packaging. The invention utilizes the paint-peelable film-making technology to prepare a single-layer or multi-layer composite film, the method is simple, the preparation cost of the composite film is greatly reduced, and the stripping process is simple, without using a release agent, an organic solvent and an acid-base solution.

Description

technical field [0001] The invention relates to the technical field of film processing, in particular to a preparation method of a polymer composite film. Background technique [0002] Films made of polyvinyl chloride, polyethylene, polypropylene, polystyrene, and other resins used in packaging and as laminations. Plastic packaging and plastic packaging products are taking an increasing share in the market, especially composite plastic flexible packaging, which has been widely used in food, medicine, chemical and other fields. There are many methods for forming plastic films, such as calendering, casting, blow molding, and stretching. These production methods have the characteristics of high production efficiency and large output. [0003] For multi-layer multifunctional composite films, the traditional preparation methods include: 1. Laminate the thermoplastic films that have been manufactured, and bond the layers with adhesives. 2. Adopt multi-layer co-extrusion molding,...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J5/18C09D5/03C09D5/20C09D5/16C09D163/00C09D167/00C09D127/12
CPCC08L2205/025C09D5/03C09D5/1662C09D5/1668C09D5/20C09D127/12C09D163/00C09D167/00C08L63/00C08L67/00
Inventor 伍明
Owner FOSHAN YIKEJU NEW MATERIAL CO LTD
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