Norbornene, octafluorocyclopentene and N-phenyl maleimide ternary copolymerization catalyst and ternary copolymerization method
A maleimide ternary copolymerization catalyst and maleimide ternary technology, applied in the field of polymers, can solve the problems of small molecular weight of copolymers, low degree of alternation of copolymers, and low yield of copolymers. Achieve the effects of low reaction temperature, improved solubility and toughness, and high copolymer yield
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Embodiment 1
[0025] In a three-necked flask with a dry inert atmosphere, dissolve 0.001 mol of titanocene dichloride and 0.001 mol of 8-hydroxyquinoline in 10 ml of benzene, and drop 0.001 mol of triisobutyltrialuminum into the above solution at 150 rpm , and after the drop is completed, stir at the same temperature at 30° C. for 30 minutes at the same stirring rate to obtain a titanium-aluminum complex catalyst.
[0026] Add 0.01 mole of bicyclo[2,2,1]hept-2-ene, 0.01 mole of octafluorocyclopentene and 0.01 mole of N-phenylmaleimide to several vacuum-pumped, nitrogen-filled autoclaves, Add 20ml of benzene to dissolve. According to the amount of titanocene dichloride in the catalyst, it is taken as 0.01% of the total weight of bicyclo[2,2,1]hept-2-ene, octafluorocyclopentene and N-phenylmaleimide The above-mentioned titanium-aluminum complex catalyst is injected into the above-mentioned mixture with a syringe. React at a constant temperature of 80°C and a pressure of 0.1MPa for 6 hours. ...
Embodiment 2
[0029] In a dry three-necked flask with an inert atmosphere, dissolve 0.001 mol of titanocene dichloride and 0.006 mol of α, α'-bipyridine in 10 ml of toluene, and drop 0.008 mol of triisobutylaluminum into the above-mentioned In the solution, stir at the same temperature at 50° C. for 50 minutes at the same stirring rate after dropping, to obtain a titanium-aluminum complex catalyst.
[0030] Add 0.01 mole of bicyclo[2,2,1]hept-2-ene, 0.01 mole of octafluorocyclopentene and 0.01 mole of N-phenylmaleimide to several vacuum-pumped, nitrogen-filled autoclaves, Add 20ml of toluene to dissolve. According to the amount of titanocene dichloride in the catalyst, it is taken as 0.10% of the total weight of bicyclo[2,2,1]hept-2-ene, octafluorocyclopentene and N-phenylmaleimide The above-mentioned titanium-aluminum complex catalyst is injected into the above-mentioned mixture with a syringe. React at a constant temperature of 110° C. and a pressure of 4 MPa for 6 hours. The product i...
Embodiment 3
[0032] In a three-necked flask with a dry inert atmosphere, dissolve 0.001 moles of titanocene dichloride and 0.010 moles of phenanthrocene in 10 ml of tetrahydrofuran, and drop 0.004 moles of triethylaluminum into the above solution at 150 rpm. After completion, stir at the same temperature at 30° C. for 50 minutes at the same stirring rate to obtain a titanium-aluminum complex catalyst.
[0033] Add 0.01 mole of 1-methylbicyclo[2,2,1]hept-2-ene, 0.01 mole of octafluorocyclopentene and 0.01 mole of N-phenylmaleimide to the In the autoclave, add 20ml THF to dissolve. According to the amount of titanium dichloride in the catalyst, it is the total weight of 1-methylbicyclo[2,2,1]hept-2-ene, octafluorocyclopentene and N-phenylmaleimide 0.07% of the above-mentioned titanium-aluminum complex catalyst was injected into the above-mentioned mixture with a syringe. The reaction was carried out at a constant temperature of 130° C. and a pressure of 6 MPa for 1 hour. The product is po...
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