Commercial rare earth permanent magnet produced from high-abundance rare earth and preparing method thereof
A rare earth permanent magnet, high-abundance technology, applied in the direction of magnetic objects, permanent magnets, inductors/transformers/magnets, etc., can solve the problems of easy corrosion and limit the application of LaCe, so as to improve the corrosion resistance and corrosion resistance of magnets The effect of reducing the property and improving the remanence and energy product
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[0019] The specific steps of the preparation method of the commercial rare earth permanent magnet produced by using high-abundance rare earth are as follows:
[0020] 1) Follow the low H A (RE 100-a MM a )-Fe-B alloy and high H A The components of the Nd-Fe-B alloy are separately batched, and the quick-setting casting strip technology is used to obtain the flakes of the two alloys with a thickness of 0.2~0.5mm; Grinding into magnetic powder with an average particle size of 3-5 μm;
[0021] 2) The grain boundary modified phase powder is prepared by smelting, coarse crushing, and ball milling in turn, or the grain boundary modified phase powder is prepared by rapid solidification casting belt, hydrogen breaking, and jet milling in sequence. The average grain boundary modified phase powder is The particle size is 0.01~3.0μm;
[0022] 3) Mix the grain boundary modified phase powder with the magnetic powder obtained in step 1) under the protection of nitrogen, and after mixi...
Embodiment 1
[0026] 1) Will be in mass percentage, the composition is (Nd 70 (LaCe) 30 ) 29.3 B 1.03 Fe 70.68 and (PrNd) 31.5 Fe 61.93 Al 0.3 Nb 0.2 Zr 0.1 B 0.97 The main alloys are prepared separately, and the prepared raw materials are placed in the crucible of the intermediate frequency induction furnace until the vacuum degree reaches 10 -2 Start heating when Pa is above, and when the temperature of the alloy liquid rises to about 1500°C, pour the alloy liquid onto the cooling copper roller through the tundish, the speed of the roller is 2m / s, and the thickness of the flake is 0.2~0.5mm;
[0027] 2) After mixing the flakes of the two main alloys in a ratio of 5:5, the magnetic powder with an average particle size of 3.5 μm is made by hydrogen breaking and jet milling;
[0028] 3) The grain boundary phase is made into a powder with an average particle size of 1.5 μm by smelting, coarse crushing, and ball milling, and its composition is Nd 32.5 Fe 62 Cu 5.5 .
[0029]...
Embodiment 2
[0034] 1) Will be in mass percentage, the composition is (Nd 60 (LaCe) 40 ) 29.3 B 1.03 Fe 70.68 and (PrNd) 30.5 Gd 1.0 Fe 61.93 Al 0.3 Nb 0.2 Zr 0.1 B 0.97 The main alloys are prepared separately, and the prepared raw materials are placed in the crucible of the intermediate frequency induction furnace until the vacuum degree reaches 10 -2 Start heating when Pa is above, and when the temperature of the alloy liquid rises to about 1500°C, pour the alloy liquid onto the cooling copper roller through the tundish, the speed of the roller is 2m / s, and the thickness of the flake is 0.2~0.5mm;
[0035] 2) After mixing the flakes of the two main alloys in a ratio of 6:4, the magnetic powder with an average particle size of 5 μm is made by hydrogen breaking and jet milling;
[0036] 3) In terms of mass percentage, after mixing 99.9% of the main alloy powder, 0.1% of nano-Cu powder, 0.2% of aviation gasoline and 0.2% of antioxidant, the magnetic powder is oriented and formed ...
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