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Commercial rare earth permanent magnet produced from high-abundance rare earth and preparing method thereof

A rare earth permanent magnet, high-abundance technology, applied in the direction of magnetic objects, permanent magnets, inductors/transformers/magnets, etc., can solve the problems of easy corrosion and limit the application of LaCe, so as to improve the corrosion resistance and corrosion resistance of magnets The effect of reducing the property and improving the remanence and energy product

Active Publication Date: 2014-05-14
ZHEJIANG UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the ensuing corrosion problem in the application process more seriously limits the application of LaCe in rare earth permanent magnet materials.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0019] The specific steps of the preparation method of the commercial rare earth permanent magnet produced by using high-abundance rare earth are as follows:

[0020] 1) Follow the low H A (RE 100-a MM a )-Fe-B alloy and high H A The components of the Nd-Fe-B alloy are separately batched, and the quick-setting casting strip technology is used to obtain the flakes of the two alloys with a thickness of 0.2~0.5mm; Grinding into magnetic powder with an average particle size of 3-5 μm;

[0021] 2) The grain boundary modified phase powder is prepared by smelting, coarse crushing, and ball milling in turn, or the grain boundary modified phase powder is prepared by rapid solidification casting belt, hydrogen breaking, and jet milling in sequence. The average grain boundary modified phase powder is The particle size is 0.01~3.0μm;

[0022] 3) Mix the grain boundary modified phase powder with the magnetic powder obtained in step 1) under the protection of nitrogen, and after mixi...

Embodiment 1

[0026] 1) Will be in mass percentage, the composition is (Nd 70 (LaCe) 30 ) 29.3 B 1.03 Fe 70.68 and (PrNd) 31.5 Fe 61.93 Al 0.3 Nb 0.2 Zr 0.1 B 0.97 The main alloys are prepared separately, and the prepared raw materials are placed in the crucible of the intermediate frequency induction furnace until the vacuum degree reaches 10 -2 Start heating when Pa is above, and when the temperature of the alloy liquid rises to about 1500°C, pour the alloy liquid onto the cooling copper roller through the tundish, the speed of the roller is 2m / s, and the thickness of the flake is 0.2~0.5mm;

[0027] 2) After mixing the flakes of the two main alloys in a ratio of 5:5, the magnetic powder with an average particle size of 3.5 μm is made by hydrogen breaking and jet milling;

[0028] 3) The grain boundary phase is made into a powder with an average particle size of 1.5 μm by smelting, coarse crushing, and ball milling, and its composition is Nd 32.5 Fe 62 Cu 5.5 .

[0029]...

Embodiment 2

[0034] 1) Will be in mass percentage, the composition is (Nd 60 (LaCe) 40 ) 29.3 B 1.03 Fe 70.68 and (PrNd) 30.5 Gd 1.0 Fe 61.93 Al 0.3 Nb 0.2 Zr 0.1 B 0.97 The main alloys are prepared separately, and the prepared raw materials are placed in the crucible of the intermediate frequency induction furnace until the vacuum degree reaches 10 -2 Start heating when Pa is above, and when the temperature of the alloy liquid rises to about 1500°C, pour the alloy liquid onto the cooling copper roller through the tundish, the speed of the roller is 2m / s, and the thickness of the flake is 0.2~0.5mm;

[0035] 2) After mixing the flakes of the two main alloys in a ratio of 6:4, the magnetic powder with an average particle size of 5 μm is made by hydrogen breaking and jet milling;

[0036] 3) In terms of mass percentage, after mixing 99.9% of the main alloy powder, 0.1% of nano-Cu powder, 0.2% of aviation gasoline and 0.2% of antioxidant, the magnetic powder is oriented and formed ...

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Abstract

The invention discloses a commercial rare earth permanent magnet produced from high-abundance rare earth and a preparing method of the commercial rare earth permanent magnet. The commercial rare earth permanent magnet comprises a main phase and a grain boundary modification phase, wherein the main phase comprises low H (RE100-aMMa)-Fe-B alloy and high H Nd-Fe-B alloy. According to the commercial rare earth permanent magnet, two kinds of main alloy is adopted, the ingredients of the magnet are controlled, a stable 2:14:1 phase is formed by the high-abundance rare earth, and decomposing will not happen in the sintering process; the Cu element high in electrode potential is added into the grain boundary modification phase, the corrosion resistance of the magnet is improved, and meanwhile the microstructure of the magnet can be optimized by the grain boundary modification phase. According to the method, the two main alloy method is combined with the grain boundary modification technology, the advantages of both the two main alloy method and the grain boundary modification technology are achieved simultaneously, the problems that because of addition of the high-abundance rare earth, the corrosion resistance, the residual magnetism and the magnetic energy product of the magnet are reduced are solved, and the prepared rare earth permanent magnet meets the application requirements of commercial magnets.

Description

technical field [0001] The invention relates to the technical field of rare earth permanent magnet materials, in particular to a commercial rare earth permanent magnet produced by using high-abundance rare earth and a preparation method thereof. Background technique [0002] The proven industrial reserves of rare earth resources in the world are 9,900-10,000 tons. In 2008, the world's rare earth consumption was 130,000 tons. It is predicted that by 2015, the world's rare earth consumption will be about 21 tons. If the annual rare earth consumption is 300,000 tons According to calculations, the global light rare earth metals are only available for about 300 years. Moreover, with social development and scientific and technological progress, the amount of rare earths is increasing year by year, and the global rare earth resources are being consumed too quickly, leading to the "rare earth crisis theory". China is a major rare earth country in the world, so we should pay more at...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01F1/057H01F7/02H01F41/02B22F3/16
Inventor 严密高翠金佳莹王新华
Owner ZHEJIANG UNIV
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