The invention discloses an electrostatic spinning device available for 3D (three-dimensional) printing. The electrostatic spinning device comprises a spherical high-voltage electrode, a receiving plate, an insulating connection part, a fixing support, a head, a head heating ring, a miniature screw rod, a coupler, a stepping motor, a heat insulation gasket, a plug, a spinning nozzle, a spinning nozzle heating ring, a ground electrode, a spherical ground electrode, a workpiece, a high-voltage electrostatic generator and the like. When the electrostatic spinning device is in operation, the miniature screw rod rotates to convey melt or solution to the spinning nozzle; the spinning nozzle is in threaded connection with the head, the spherical ground electrode is half wrapped at the lower end of the spinning nozzle, and the melt or solution uniformly flows from the surface of the spherical ground electrode to the lower end of the spherical ground electrode through notches peripherally distributed at the lower end of the spinning nozzle. Since the high-voltage electrode and the ground electrode are both spherical electrodes, the defect of proneness to blockage of needle eyes or pores in normal spinning equipment is overcome, and compared with point electrodes, the spherical electrodes have the advantages that point discharge is alleviated, and higher voltage strength can be achieved under the condition of equal distance.