The invention discloses a stator end electric shielding structure of a synchronous generator. The stator end electric shielding structure of the synchronous generator comprises an outer shielding ring, a cushion block, a stator coil, an inner shielding ring, a stator pressing ring and a stator tooth support. The stator pressing ring compresses the stator tooth support and is fixed on the end portion of a stator core through bolts, the inner shielding ring is fixed on the stator pressing ring through bolts, and the outer shielding ring is fixed with the inner shielding ring through bolts and the cushion block. The end portion of the stator coil is placed among the inner shielding ring, the outer shielding ring and the stator tooth support. The inner shielding ring, the outer shielding ring and the stator tooth support are made of nonmagnetic material copper. The stator end electric shielding structure of the synchronous generator is simple in structure and high in reliability, magnetic leakage on the end portion of the stator coil is reduced, heating of the stator pressing ring and heating of a rotor retaining ring are reduced, and the operation reliability of the synchronous generator is improved.