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Super-hydrophobic heat-resistant coating for aluminum alloy and preparation method of super-hydrophobic heat-resistant coating

A technology of super-hydrophobic coating and heat-resistant coating, applied in metal material coating process, coating, device for coating liquid on the surface, etc. It is difficult to stabilize production and other problems, and achieve the effect of preventing thermal migration and improving heat resistance

Inactive Publication Date: 2022-04-26
严平
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, chromium-containing chemical conversion coatings are highly efficient and widely used, and Dacromet coatings are more typical. However, such coatings will release carcinogenic hexavalent chromium during production and use, which is highly toxic to organisms.
[0003] In addition, aluminum alloys are also lacking in heat resistance.
At present, the heat-resistant aluminum alloy materials on the market are mainly manifested in the instability of the alloy composition, accompanied by defects such as flashes, burrs, cracks, and inclusions, which lead to the physical properties of the aluminum alloy not meeting the requirements of users and the market, thus causing serious problems for both the supply and demand sides. big economic loss
For heat-resistant alloy materials produced by general manufacturers, the focus of production is mainly to control various harmful elements that affect heat resistance, and in order to improve performance, some alloy elements will be added in an appropriate amount. The requirements are relatively strict, which makes it difficult for many manufacturers to produce stably or It cannot be produced, which also makes the cost of heat-resistant alloy materials increase sharply, which brings a certain economic burden to the demand enterprises

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] A method for preparing a superhydrophobic heat-resistant coating for an aluminum alloy, the method for preparing a superhydrophobic heat-resistant coating for an aluminum alloy mainly includes the following preparation steps:

[0032] (1) Spraying pretreatment: Polish the aluminum alloy with 220-mesh sandpaper for 5 minutes, soak it in an alkali cleaning solution twice the quality of the aluminum alloy, and the mass ratio of sodium carbonate, sodium silicate, sodium phosphate and deionized water in the alkali cleaning solution is 1:0.5:1:18, after soaking at 70°C for 8 minutes, rinse with deionized water for 3 minutes to obtain a pretreated aluminum alloy; Mix water at a mass ratio of 1:122, add glacial acetic acid until the pH of the solution is 4, let stand for hydrolysis for 24 hours, and make a silane solution; place the pretreated aluminum alloy on a glass plate, and spray a silane solution 0.3 times the mass of the pretreated aluminum alloy , and then cured at 90°...

Embodiment 2

[0038] A method for preparing a superhydrophobic heat-resistant coating for an aluminum alloy, the method for preparing a superhydrophobic heat-resistant coating for an aluminum alloy mainly includes the following preparation steps:

[0039] (1) Spraying pretreatment: Polish the aluminum alloy with 240-mesh sandpaper for 3 minutes, soak it in an alkali cleaning solution 2.14 times the quality of the aluminum alloy, and the mass ratio of sodium carbonate, sodium silicate, sodium phosphate and deionized water in the alkali cleaning solution is 1:0.5:1:18, after soaking at 75°C for 6 minutes, rinse with deionized water for 5 minutes to obtain a pretreated aluminum alloy; Mix water at a mass ratio of 1:123, add glacial acetic acid until the pH of the solution is 4.5, let stand for hydrolysis for 26 hours, and make a silane solution; place the pretreated aluminum alloy on a glass plate, and spray a silane solution that is 0.4 times the mass of the pretreated aluminum alloy , and th...

Embodiment 3

[0045] A method for preparing a superhydrophobic heat-resistant coating for an aluminum alloy, the method for preparing a superhydrophobic heat-resistant coating for an aluminum alloy mainly includes the following preparation steps:

[0046] (1) Spraying pretreatment: Polish the aluminum alloy with 240-mesh sandpaper for 5 minutes, soak it in an alkali cleaning solution that is 3 times the quality of the aluminum alloy, and the mass ratio of sodium carbonate, sodium silicate, sodium phosphate and deionized water in the alkali cleaning solution is 1:0.5:1:18, after soaking at 80°C for 5 minutes, rinse with deionized water for 7 minutes to obtain a pretreated aluminum alloy; Mix water at a mass ratio of 1:124, add glacial acetic acid until the pH of the solution is 5, let stand for hydrolysis for 28 hours, and make a silane solution; place the pretreated aluminum alloy on a glass plate, and spray a silane solution 0.5 times the mass of the pretreated aluminum alloy , and then cu...

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PUM

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Abstract

The invention discloses a super-hydrophobic heat-resistant coating for an aluminum alloy and a preparation method of the super-hydrophobic heat-resistant coating, and relates to the technical field of coatings. The heat-resistant coating is formed on the surface of the aluminum alloy through the spraying pretreatment process and the second-time spraying treatment in sequence, the heat-resistant coating and the aluminum alloy form a firm cross-linked interpenetrating network structure, the heat resistance of the coating is improved, and the phenomenon that the service life of the aluminum alloy is shortened in a high-temperature environment is reduced; and then third spraying treatment is conducted, a corrosion inhibitor serves as an inner core solution, stearic acid serves as a shell solution, a super-hydrophobic coating is formed through coaxial electrostatic spraying, the corrosion inhibitor is prepared from isoquinocarboxylic acid, dipropylene triamine and p-methoxyphenyl thiourea, the surface of the aluminum alloy is isolated from an environment medium, and corrosion of an acid medium and chloride ions is inhibited. The prepared super-hydrophobic heat-resistant coating for the aluminum alloy has the heat-resistant, super-hydrophobic and corrosion-resistant effects.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to a superhydrophobic heat-resistant coating for aluminum alloys and a preparation method thereof. Background technique [0002] Aluminum alloy is a kind of metal widely used in the industry. It has excellent characteristics such as light weight, high strength, and good machinability. It is widely used in high-tech fields such as aerospace and marine tooling. In the environment, aluminum alloy is extremely prone to corrosion, which affects the long-term reliable operation of key components. Focusing on metal anti-corrosion coatings, countries around the world have developed a variety of aluminum alloy anti-corrosion technologies, mainly including anodic oxidation, chemical conversion coating, electroplating and chemical plating. Among them, chromium-containing chemical conversion coatings are highly efficient and widely used, and Dacromet coatings are more typical. However, such c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D183/06C09D1/00B05D1/04B05D3/10B05D3/12B05D5/00B05D7/14B05D7/24C23C4/10C23C4/129C23F11/00
CPCC09D4/00C09D183/06C09D1/00C23C4/129C23C4/10C23F11/00B05D7/14B05D7/24B05D1/04B05D5/00B05D3/12B05D3/102B05D2202/25C08G77/14
Inventor 严平
Owner 严平
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