A method for suppressing cyanide dissolution of copper minerals in refractory copper-bearing gold ores
A technology for refractory and gold mines, applied in the direction of improving process efficiency, etc., to achieve the effects of improving utilization rate, reducing cyanide consumption, and reducing consumption
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Embodiment 1
[0021] In this embodiment, two single minerals, chalcopyrite and bornite, are treated by the method of the present invention. Grind the above two kinds of copper minerals with a three-head grinder to -200 mesh and account for 100%, respectively take a certain amount of two kinds of copper minerals (the amount of copper metal is 5g), press the liquid-solid ratio 27:1, pH=11.5 , NaCN concentration 5g / L, stirring speed 901r / min, leaching temperature 25°C, leaching time 12h for leaching test. The test results are shown in the table below.
[0022]
[0023]
[0024]
[0025] As can be seen from the above table, the addition of 0.6g / L of lead oxide reduces the leaching rate of chalcopyrite copper from 2.4% when no lead oxide is added to 1.68%, and the leaching rate of bornite copper is reduced from 2.4% when no lead oxide is added. 6.67% was reduced to 2.33%, which indicated that the addition of lead oxide inhibited the dissolution of chalcopyrite and bornite in the cyanid...
Embodiment 2
[0027] In this embodiment, the method of the present invention is used to treat a copper-containing gold concentrate in Lingbao, Henan. The main metal minerals in the copper-bearing gold concentrate are chalcopyrite, sphalerite and pyrite, the main gangue minerals are quartz and muscovite, and the gold and copper grades are 38.97g / t and 2.35% respectively. test attached figure 1 Carried out, the test results are shown in the table below.
[0028] Lead oxide / kg / t Gold leaching slag / g / t Gold leaching rate / % Copper leaching rate / % Sodium cyanide unit consumption / kg / t 0.0 3.94 89.9 33.19 19.28 4.0 2.91 92.53 27.66 15.88
[0029] It can be seen from the above table that the addition of 4.0kg / t of lead oxide reduces the copper leaching rate from 33.19% to 27.66% when no lead oxide is added, and the gold leaching rate increases from 89.90% when no lead oxide is added to 92.53%, and the cyanide consumption is also reduced from 19.28kg / t without ...
Embodiment 3
[0031] In this embodiment, the method of the present invention is used to treat three kinds of copper-containing gold concentrates in Fujian (respectively A mine, B mine and C mine). The metal minerals in these three kinds of copper-bearing gold concentrates are mainly pyrite, with a roughly content of about 40%, followed by chalcopyrite, galena, pyrrhotite, and copper blue and tetrahedrite, sphalerite. Zinc ore and trace lead sulfur salt minerals. The gangue minerals are mainly quartz, with a content of about 35%, followed by sericite (white) mica (about 15-25%), and the rest are chlorite (about 5-10%), kaolinite and calcite, a small amount of feldspar, etc. , There are silver minerals (natural silver and argentite, etc.) when there is obvious presence of carbon. The grades of gold and copper in mine A, mine B and mine C are 115.2g / t, 2.48%, 51.8g / t, 1.89%, 109.2g / t, 0.48%, respectively.
[0032] Routine test conditions: leaching time is 48 hours, leaching sodium cyanide co...
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