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Manufacturing method of high manganese high nitrogen low nickel non-magnetic stainless steel and product thereof

A technology of non-magnetic stainless steel and manufacturing method, applied in the field of steel, can solve the problems of irreversible discoloration of materials, failure to pass the magnetic inspection, increase of processes, etc., and achieve the effect of being beneficial to absorption, processing performance and wear resistance, and reducing inclusions

Active Publication Date: 2017-06-20
宁波市博祥新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] However, although this type of stainless steel is non-magnetic at room temperature, it will produce obvious magnetism after deep drawing and other mechanical processing. unpassable problem
At present, the only way to eliminate the above-mentioned mechanical magnetism is to perform secondary annealing treatment on metal parts. However, this treatment not only increases the process and increases the cost, but also causes irreversible discoloration of the material due to high temperature, which cannot meet the needs of clothing and bags. Requirements for metal fittings or accessories

Method used

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  • Manufacturing method of high manganese high nitrogen low nickel non-magnetic stainless steel and product thereof

Examples

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Effect test

Embodiment 1

[0036] A high-manganese, high-nitrogen, low-nickel non-magnetic stainless steel, characterized in that the stainless steel is a single-phase austenitic stainless steel, and its chemical composition and mass percentage are shown in Table 1.

[0037] Table 1 Results of melting composition analysis of stainless steel in Example 1

[0038] C%S%P%Si% Mn% Ni%Cr%Cu%N% Mo% Nb% Target value----1811011.451 Measured value 0.030.010.0100.4517.880.9910.020.991.334.970.99

[0039] The stainless steel is deep-drawn into a ring fitting with a mass of 2g and a diameter of 25mm, with a magnetic permeability ≤1.0×10-6H / m, and a smooth surface with silver-white metallic luster.

[0040] The manufacturing method of the above-mentioned high manganese, high nitrogen and low nickel non-magnetic stainless steel includes the following steps:

[0041] 1. Preparation of ferrochromium nitride: In a nitrogen glove box, put 100 mesh metal chromium powder and metal iron powder into a stainless steel ball mill at...

Embodiment 2

[0054] A high-manganese, high-nitrogen, low-nickel non-magnetic stainless steel, characterized in that the stainless steel is a single-phase austenitic stainless steel, and its chemical composition and mass percentage are shown in Table 2.

[0055] Table 2 Analysis results of melting composition of stainless steel in Example 2

[0056] C%S%P%Si% Mn% Ni%Cr%Cu%N% Mo% Nb% Target value----160.5140.5220.5 Measured value 0.040.010.0120.5515.920.4913.970.501.841.980.50

[0057] The stainless steel is deep-drawn into a button with a mass of 1g and a diameter of 10mm, the magnetic permeability is ≤1.0×10-6H / m, and the surface is smooth with silver-white metallic luster.

[0058] The manufacturing method of the above-mentioned high-manganese, high-nitrogen, low-nickel non-magnetic stainless steel includes the following steps:

[0059] 1. Preparation of ferrochromium nitride: In a nitrogen glove box, put 100-200 mesh metal chromium powder and metal iron powder into a stainless steel ball mil...

Embodiment 3

[0072] A high-manganese, high-nitrogen, low-nickel non-magnetic stainless steel, characterized in that the stainless steel is a single-phase austenitic stainless steel, and its chemical composition and mass percentage are shown in Table 3.

[0073] Table 3 Results of melting composition analysis of stainless steel in Example 3

[0074] C%S%P%Si% Mn% Ni%Cr%Cu%N% Mo% Nb% Target value----171.5110.31.80.50.3 Measured value 0.020.010.0150.9116.941.4810.950.301.710.490.30

[0075] The stainless steel is deep-drawn into a square fitting with a mass of 5g and a side length of 20mm, with a magnetic permeability of ≤1.0×10 -6 H / m, smooth surface with silver-white metallic luster.

[0076] The manufacturing method of the above-mentioned high manganese, high nitrogen and low nickel non-magnetic stainless steel includes the following steps:

[0077] 1. Preparation of ferrochromium nitride: In a nitrogen glove box, put 100-200 mesh metal chromium powder and metal iron powder into a stainless st...

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Abstract

The invention provides a manufacturing method of a high manganese high nitrogen low nickel non-magnetic stainless steel and a product thereof. The stainless steel is single phase austenite stainless steel which comprises the following chemical components in percentages by mass: greater than 0 but less than or equal to 0.1% of C, less than or equal to 0.01% of S, less than or equal to 0.015% of P, greater than 0 but less than or equal to 1.0% of Si, greater than or equal to 16% but less than or equal to 18% of Mn, greater than 0 but less than or equal to 2% of Ni, greater than or equal to 10% but less than or equal to 14% of Cr, greater than or equal to 1% but less than or equal to 2% of N, greater than or equal to 0.3% but less than or equal to 1% of Cu, greater than or equal to 0.3% but less than or equal to 5% of Mo, greater than or equal to 0.3% but less than or equal to 1% of Nb and the balance of Fe. The manufacturing method comprises the following steps: heating and smelting raw materials, and performing decarbonization, desulfuration and deoxygenation; raising the temperature to 1600 DEG C and adding nickel; adjusting the temperature of a bath to 1550 DEG C, and adding ferromolybdenum, ferrocolumbium and a metal copper; adding a desoxidant for secondary deoxidization, introducing nitrogen, adjusting the temperature of the bath to 1610-1620 DEG C, and adding nitrogen containing ferrochromium; adjusting the temperature of the bath to 1150-1250 DEG C, introducing nitrogen, adding nitrided ferromanganese, pouring, quenching and air cooling, and machining to form a panel, heating the panel to 650-700 DEG C, keeping the temperature for 30min, and performing furnace cooling to room temperature. The stainless steel through deep punching is still non-magnetic, and needs not to be annealed and demagnetized. The manufacturing method is high in nitrogen-increasing efficiency and low in loss of equipment.

Description

[0001] 【Technical Field】 [0002] The invention relates to the field of iron and steel, in particular to a method for manufacturing high-manganese, high-nitrogen, low-nickel non-magnetic stainless steel and its products. [0003] 【Background technique】 [0004] Austenitic stainless steel is an interstitial solid solution formed by elements such as chromium and nickel in γ-Fe. In order to keep the chromium-nickel steel completely austenitic, the nickel content in the steel should be no less than the value of the following empirical formula: [0005] Ni(%)=1.1(Cr+Mo+1.5Si+1.5Nb)-0.5Mn-30C-8.2 [0006] The main characteristics of austenitic stainless steel are: non-magnetic at room temperature, low yield ratio of steel, good plasticity, good welding performance, easy smelting and casting and hot forming; its composition is characterized by high chromium (≥17 %), nickel (8%-25%) and other elements that improve corrosion resistance (such as molybdenum, copper, silicon, niobium, titanium, etc...

Claims

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Application Information

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IPC IPC(8): C22C38/58C22C38/42C22C38/44C22C38/48C22C38/02C22C27/06C21C7/06C21C7/064C21C7/068B22C9/04C21D8/02C22C22/00B22F3/16C21C5/52C22C35/00
CPCB22C9/04B22F3/16C21C5/005C21C5/5264C21C7/06C21C7/064C21C7/068C21D8/02C22C22/00C22C27/06C22C35/00C22C38/001C22C38/004C22C38/02C22C38/42C22C38/44C22C38/48C22C38/58Y02P10/20
Inventor 梅海滨
Owner 宁波市博祥新材料科技有限公司
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